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Allylboration occurs with an allylic rearrangement.  We have discovered a novel a-allylation in the presence of Lewis acids.  We are developing a chiral version of this reaction and are also applying this protocol for the synthesis of complex molecules.

 

Chem. Commun. 2005, 1988

 

This reaction occurs via an oxonia-Cope rearrangement.

 

 

 

 

 

 

 

 

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