The Shapes of Molecules


  1. On the basis of the VSEPR model, which of the following molecules is linear?

    1. H2O
    2. BF3
    3. BeF2
    4. CH4
    5. none of these

  2. The molecular shape of H3O+ is:

    1. linear.
    2. planar.
    3. see-saw.
    4. trigonal planar.
    5. trigonal pyramidal.

  3. Which of the following is a planar molecule or ion?

  4. Which of the following molecules or ions is not linear?

    The next three questions refer to the molecule OXeF4 with a Lewis dot structure shown below.

  5. The formal charge on the Xe atom is:

    1. -2
    2. -1
    3. 0
    4. +1
    5. +2

  6. The geometry of the OXeF4 molecule is:

    1. trigonal bipyramidal.
    2. octahedral.
    3. square pyramidal.
    4. square planar.
    5. none of the above.

  7. The number of bonding pair-to-bonding pair repulsions in OXeF4 is:

    1. 0
    2. 2
    3. 4
    4. 8
    5. 12

  8. The molecular shape of SeF4 is:

    1. see-saw.
    2. square planar.
    3. tetrahedral.
    4. square pyramidal.
    5. impossible to predict.

  9. Which of the following hybrid orbitals forms bond angles of approximately 109o?

    1. sp
    2. sp2
    3. sp3
    4. sp3d
    5. sp3d2

  10. When the molecules H2O, CH4, and NH3 are arranged in order of increasing bond angle, the correct sequence is:

    1. H2O, CH4, NH3
    2. H2O, NH3, CH4
    3. NH3, H2O, CH4
    4. CH4, NH3, H2O
    5. CH4, H2O, NH3

  11. Which of the following molecules has the smallest angle between adjacent bonds?

    1. CO2
    2. CH4
    3. H2O
    4. NH3
    5. PH3

  12. The shape of ICl4- is:

    1. octahedral.
    2. see saw.
    3. square planar.
    4. tetrahedral.
    5. square pyramidal.

  13. What are the approximate values of the bond angles, a and b, in the ion illustrated below?

    1. a is ~90o and b is ~90o
    2. a is ~109o and b is ~109o
    3. a is ~109o and b is ~120o
    4. a is ~120o and b is ~109o
    5. a is ~90o and b is ~180o

  14. The molecules NF3, BF3, and ClF3 have similar molecular formulas but different molecular geometries. Use VSEPR to predict their molecular shapes.

    1. NF3 trigonal pyramidal; BF3 trigonal planar; ClF3 T-shaped
    2. NF3 T-shaped; BF3 trigonal planar; ClF3 trigonal pyramidal
    3. NF3 trigonal planar; BF3 T-shaped; ClF3 trigonal pyramidal
    4. NF3 T-shaped; BF3 trigonal pyramidal; ClF3 trigonal planar
    5. NF3 trigonal pyramidal; BF3 T-shaped; ClF3 trigonal planar

  15. Which of the following best describes the shape and polarity of the carbon disulfide, CS2, molecule?

    1. bent and polar
    2. linear and non-polar
    3. pyramidal and polar
    4. bent and non-polar
    5. linear and polar

  16. The shape of XeF4 is:

    1. tetrahedral.
    2. see-saw.
    3. square pyramidal.
    4. trigonal pyramidal.
    5. square planar.

  17. Which of the following molecules or ions is nonplanar, i.e., has at least one atom that is not in the same plane as the others?

    1. BH3
    2. ClF3
    3. NF3
    4. SO3
    5. CO32-

  18. On the basis of the VSEPR model, which of the following triatomic molecules has the smallest angle between the two bonds?

    1. CO2
    2. H2O
    3. SO2
    4. O3
    5. CH4

  19. For the amino acid alanine, what is the bond angle about the indicated carbon atom?

    1. 109.5o
    2. 120o
    3. 180o
    4. 90o
    5. 360o

  20. Identify the molecular geometry of formaldehyde, CH2O.

    1. linear
    2. trigonal planar
    3. bent
    4. tetrahedral
    5. trigonal bipyramidal


Answers

  1. C
  2. E
  3. E
  4. B
  5. D
  6. C
  7. D
  8. A
  9. C
  10. B
  11. C
  12. C
  13. C
  14. A
  15. B
  16. E
  17. C
  18. B
  19. A
  20. B