The Shapes of Molecules
- On the basis of the VSEPR model, which of the following molecules is linear?
- H2O
- BF3
- BeF2
- CH4
- none of these
- The molecular shape of H3O+ is:
- linear.
- planar.
- see-saw.
- trigonal planar.
- trigonal pyramidal.
- Which of the following is a planar molecule or ion?

- Which of the following molecules or ions is not linear?

The next three questions refer to the molecule OXeF4 with a Lewis dot structure shown below.

- The formal charge on the Xe atom is:
- -2
- -1
- 0
- +1
- +2
- The geometry of the OXeF4 molecule is:
- trigonal bipyramidal.
- octahedral.
- square pyramidal.
- square planar.
- none of the above.
- The number of bonding pair-to-bonding pair repulsions in OXeF4 is:
- 0
- 2
- 4
- 8
- 12
- The molecular shape of SeF4 is:
- see-saw.
- square planar.
- tetrahedral.
- square pyramidal.
- impossible to predict.
- Which of the following hybrid orbitals forms bond angles of approximately 109o?
- sp
- sp2
- sp3
- sp3d
- sp3d2
- When the molecules H2O, CH4, and NH3 are arranged in order of increasing bond angle, the correct sequence is:
- H2O, CH4, NH3
- H2O, NH3, CH4
- NH3, H2O, CH4
- CH4, NH3, H2O
- CH4, H2O, NH3
- Which of the following molecules has the smallest angle between adjacent bonds?
- CO2
- CH4
- H2O
- NH3
- PH3
- The shape of ICl4- is:
- octahedral.
- see saw.
- square planar.
- tetrahedral.
- square pyramidal.
- What are the approximate values of the bond angles, a and b, in the ion illustrated below?

- a is ~90o and b is ~90o
- a is ~109o and b is ~109o
- a is ~109o and b is ~120o
- a is ~120o and b is ~109o
- a is ~90o and b is ~180o
- The molecules NF3, BF3, and ClF3 have similar molecular formulas but different molecular geometries. Use VSEPR to predict their molecular shapes.
- NF3 trigonal pyramidal; BF3 trigonal planar; ClF3 T-shaped
- NF3 T-shaped; BF3 trigonal planar; ClF3 trigonal pyramidal
- NF3 trigonal planar; BF3 T-shaped; ClF3 trigonal pyramidal
- NF3 T-shaped; BF3 trigonal pyramidal; ClF3 trigonal planar
- NF3 trigonal pyramidal; BF3 T-shaped; ClF3 trigonal planar
- Which of the following best describes the shape and polarity of the carbon disulfide, CS2, molecule?
- bent and polar
- linear and non-polar
- pyramidal and polar
- bent and non-polar
- linear and polar
- The shape of XeF4 is:
- tetrahedral.
- see-saw.
- square pyramidal.
- trigonal pyramidal.
- square planar.
- Which of the following molecules or ions is nonplanar, i.e., has at least one atom that is not in the same plane as the others?
- BH3
- ClF3
- NF3
- SO3
- CO32-
- On the basis of the VSEPR model, which of the following triatomic molecules has the smallest angle between the two bonds?
- CO2
- H2O
- SO2
- O3
- CH4
- For the amino acid alanine, what is the bond angle about the indicated carbon atom?

- 109.5o
- 120o
- 180o
- 90o
- 360o
- Identify the molecular geometry of formaldehyde, CH2O.
- linear
- trigonal planar
- bent
- tetrahedral
- trigonal bipyramidal
Answers
- C
- E
- E
- B
- D
- C
- D
- A
- C
- B
- C
- C
- C
- A
- B
- E
- C
- B
- A
- B