Writing Equilibrium Expressions
In order to write the equilibrium expression for a system in a state of equilibrium you need to know:
The general equilibrium expression for a reaction:
is written as:
The brackets "[ ]" represent the concentration of the species (moles per liter or molarity). "a, b, c, and d" represent the coefficients used to balance the equation. The "c" in Kc indicates that the value of K is determined using the concentrations of each species.
There are two cases when a species is not shown in the equilibrium expression:
When one or more of the species in a system exists in the gaseous phase, the partial pressure of that species can be used in the equilibrium expression Dissolved species are still expressed as moles per liter (molarity).
Examples of equilibrium expressions Kc for a
variety of equilibrium systems follow. When one or more gaseous substances are
involved, the Kp expression is also given.