Selected Publications

1. The Bicyclo[3.2.2] Nonatrienyl Anion. The Anionic Analog of the
Norborn-adienyl Cation. Grutzner, J. B.; Winstein, S. J. Am. Chem. Soc.
1968, 90, 6562-6564.

2. Nuclear Magnetic Resonance Spectroscopy: 13C Spectrum of the Dimer of
Cyclooctatetraene. Grohmann, K.; Grutzner, J. B.; Roberts, J. D.
Tetrahedron Letters 1969, 917-918.

3. Natural Abundance 13C Nuclear Magnetic Resonance Spectra of Terpenes and
Carotenes. Jautelat, M.; Grutzner, J. B.; Roberts, J. D. Proc. Nat. Acad.
Sci. 1970, 65, 288-292.

4. Evidence for the Existence of the Trichlorosilyl Anion. Benkeser, R. A.;
Foley, K. M.; Grutzner, J. B.; Smith, W. E. J. Am. Chem. Soc. 1970, 92,
697-698.

5.  Bicycloaromaticity: The Stability and Rearrangement of the
Bicyclo[3.2.2] Nonatrienyl Cation. Grutzner, J. B.; Winstein, S. J. Am.
Chem. Soc. 1970, 92, 3186-3187.

6.  Direct Observation of Degenerate 9-Methyl-9-Barbaralyl Cation. Ahlberg,
P.; Grutzner, J. B.; Harris, D. L.; Winstein, S. J. Am. Chem. Soc. 1970,
92, 3478-3480.

7.  Nuclear Magnetic Resonance Spectroscopy 13C Chemical Shifts in
Norbornyl Derivatives. Grutzner, J. B.; Jautelat, M.; Dence, J. B.; Smith,
R. A.; Roberts, J. D. J. Am. Chem. Soc. 1970, 92, 7107-7120.

8.  The Use of 13C NMR (CMR) Spectroscopy in Biosynthetic Studies.
Incorporation of  Carboxyl- and Methyl 13C Labelled Acetates into
Cephalosporin. Neuss, N.; Nash, C. N.; Lemke, P. A.; Grutzner, J. B. J. Am.
Chem. Soc. 1971, 93, 2337-2339.

9.  Photochemistry of Bichromophoric Molecules. Intramolecular
Cycloaddition and cis-trans Isomerization of 6-Phenyl-2-hexene in Solution.
Ferree, W.; Grutzner, J. B.; Morrison, H. A. J. Am. Chem. Soc. 1971, 93,
5502-5512.

10. Studies in Magnetic Resonance. X. The Spectroscopy of Carbanions and
the Effect of Ion Pairing on Chemical Shifts. Grutzner, J. B.; Lawlor, J.
M.; Jackman, L. M. J. Am. Chem. Soc. 1972, 94, 2306-2315.

11.  Bicycloaromaticity: The Stability and Rearrangements of the
Bicyclo[3.2.2] Nonatrienyl Anion and Cation. Grutzner, J. B.; Winstein, S.
J. Am. Chem. Soc. 1972, 94, 2200-2208.

12.  Synthesis of Tetracyclo[11.1.03,50.7,9]tetradecan-11-ols, Possible
Hepta-homotrophylium Ion Precursors. Thies, R. A.; Gasic, M.; Whalen, D.;
Grutzner, J. B.; Sakai, M.; Johnson, B.; Winstein, S. J. Am. Chem. Soc.
1972, 94, 2262-2269.

13.  1H  and 13C Nuclear Resonance Spectra of Cyclopentadienyl Magnesium
Compounds in Tetrahydrofuran. Ford, W. T.; Grutzner, J. B. J. Org. Chem.
1972, 37, 2561-2564.

14.  The Addition of Dibromocarbene to 1-Methoxynaphthalene. Moncur, M. V.;
Grutzner, J. B. Chem. Commun. 1972, 667-668.

15.  The Use of 13C NMR (CMR), Spectroscopy in Biosynthetic Studies of
?-Lactam Antibiotics. Neuss, N.; Nash, C. N.; Lemke, P. A.; Grutzner, J. B.
Proc. Roy. Soc. B. 1971, 179, 335-344.

16.  Carbon-13 NMR Spectroscopy and its Application to Biological Systems.
Grutzner, J. B. Lloydia 1972, 35, 375-398.

17.  Incorporation of 2R, S-(3S)-[4-13C]-Valine into Cephalosporin C.
Neuss, N.; Nash, C. N.; Baldwin, J.E.; Lemke, P. A.; Grutzner, J. B. J.
Amer. Chem. Soc. 1973, 95, 3797.

18.  Photochemistry of Bichromophoric Systems: Solution Phase
Photochemistry of 2-Methylenebenznorbornene.  Scully, F.; Grutzner, J. B.;
Morrison, H. A. J. Amer. Chem. Soc. 1973, 95, 5100-5104.

19.  Laboratory Manual: A Laboratory Manual for General Chemistry (3rd
Edition) by Larson, E.; Wolinsky, J.; Ahlgren, K.; Grutzner, J. B., 1973.

20.  The Bicyclo[3.2.2]nona-2, 6-dienyl Carbanion.  Preparation, Basicity
and Laticyclic Stabilization. Moncur, M. V.; Grutzner, J. B. J. Am. Chem.
Soc. 1973, 95, 6449-6451.

21.  Proton NMR Spectra of 1-Substituted Acenaphthenes and Other Systems of
Well Defined Geometry. Fay, C. K.; Grutzner, J. B.; Johnson, L. F.;
Sternhell, S.; Westerman, P. W. J. Org. Chem. 1973, 38, 3122-3136.

22.  Concerning the Structure of Allylic Grignard Reagents. Hutchinson, D.
A.; Beck, K. R.; Benkeser, R. A.; Grutzner, J. B. J. Am. Chem. Soc. 1973,
95, 7075-7082.

23.  Book Review: "Theory and Interpretation of Magnetic Resonance
Spectra", by Dixon, W. T.  Canad. J. Spectroscopy, 1974, 19, 104.

24. The Degenerate Rearrangement of the Benzo-6,7-bicyclo[3.2.2]nonatrienyl
Anion - The Relative Stability of A Benzylic and an Allylic Anion.  Moncur,
M. V.; Grutzner, J. B.; Eisenstadt, A. J. Org. Chem. 1974, 39, 1604-1607.

25.  Applications and Limitations of Second Order Effects in Off Resonance
Decoupled 13C Nuclear Magnetic Resonance Spectra.  Grutzner, J. B. Chem.
Commun. 1974, 64-65.

26.  Experimental and Theoretical Vicinal 13C-13C Coupling Constants.
Doddrell, D.; Burfitt, I.; Grutzner, J. B.; Barfield, M. J. Amer. Chem.
Soc. 1974, 96. 1241-1243.

27.  Coherent Broad-band Decoupling - An Alternative to Proton Noise
Decoupling in Carbon-13 NMR Spectroscopy.  Grutzner, J. B.; Santini, R. E.
J. Magn. Reson. 1975, 19, 173-187.

28.  The Rapid HI Cleavage of Ethers and Ketals in Acetonitrile. Catalysis
by CH3OCH2I and Preparation of Formates.  Smith, C. A.; Grutzner, J. B. J.
Org. Chem. 1976, 41, 367-370.

29.  Conformational Equilibria in Cyclohexyltrimethylstannane and
Cyclohexyltri-trimethylplumbane by Low Temperature 13C NMR Spectroscopy.
Kitching, W.; Doddrell, D.; Grutzner, J. B. J. Organomet. Chem. 1976, 107,
C5-C10.

30.  Total Systematic Noise Reduction in Fourier Transform Nuclear Magnetic
Resonance Spectrometry.  Santini, Robert E.; Grutzner, John B. Anal. Chem.
1976, 48, 941-943.

31.  A Broadband System for the Observation of NMR Spectra of any Resonance
Nucleus. Santini, R. E.; Grutzner, J. B. J. Magn. Reson. 1976, 22, 155--160.

32.  Homoallylic Interaction Involving Nitrogen Lone Pairs - A
Re-examination.  Grutzner, J. B. J. Am. Chem. Soc. 1976, 98, 6385-6387.

33.  Carbanion Chemistry - A Room Temperature Retro Diels Adler Reaction.
Bowman, E. S.; Hughes, G. B.; Grutzner, J. B. J. Am. Chem. Soc. 1976, 98,
8273-8274.

34.  Dynamic Carbon-13 Nuclear Magnetic Resonance Spectra of
Benzobullvalene and o-Toluobullvalene.  Carlsen, R. 0.; Grutzner, J. B. J.
Org. Chem. 1977, 42, 2183-2185.

35.  Phosphorus Nuclear Magnetic Resonance Studies of Phosphoglucomutase
and Its Metal Ion Complexes.  Ray, Jr., W. J.; Mildvan, A. S.; Grutzner, J.
B. Archives of BCHM BPhys. 1977, 184, 453-463.

36.  Carbon-13 NMR Spectra with Coherent Proton Decoupling, Peak Height
Distortions within Spin Multiplets.  Freeman, R.; Grutzner, J. B.; Morris,
G.; Turner, D. L. J. Am. Chem. Soc. 1978, 100, 5637-5640.

37.  Alkyl Nitrate Nitration of Active Methylene Compounds. The Nitration
of Alkylphosphonate Esters.  Feuer, H.; Van Buren, Jr., W. D.; Grutzner, J.
B. J. Org. Chem. 1978, 43, 4676-4678.

38.  Pyramidal Carbanions?  Peoples, P. R.; Trainor, T.; Grutzner, J. B.
Stereodynamics in Molecular Systems, 1979, Pergamon Press, Oxford, pp.
131--145.

39.  Structure of the 7-Phenylnorbornyl Carbanion, A. Pyramidal
Organolithium and Planar Organopotassium.  Peoples, P. R.; Grutzner, J. B.
J. Am. Chem. Soc. 1980, 102, 4709-4715.

40.  Bicycloaromaticity - A Theoretical Evaluation.  Grutzner, J. B.;
Jorgensen, W. L. J. Am. Chem. Soc. 1981, 103, 1372-1375.

41.  The Structure of Carbanions and Organolithium Reagents in Solution (A
Review Article). Abstracts of Petroleum Section.  Am. Chem. Soc., Symp.
PrePrints - Advances in Carbanion Chemistry pp. 604-610, September 1985.

42.  The Taylor Vortex - the Measurement of Viscosity in NMR Samples.
Vera, M.; Grutzner, J. B. J. Am. Chem. Soc. 1986, 108, 1304-1306.

43.  Alkylation and Oligomerization of the Lithium Enolate of
2--Norbornenone.  Horner, J. H.; Vera, M.; Grutzner, J. B. J. Org. Chem.
1986, 51, 4212-4220.

44.  Structure and Dynamic Behavior of the Lithium Enolate of Acetaldehyde
in Solution.  Wen, J. Q.; Grutzner, J. B. J. Org. Chem. 1986, 51, 4220-4224.

45. Chemical Shift Theory. Orbital Symmetry and Charge Effects on Chemical
Shifts. Grutzner, J. B. Recent Advances in Organic NMR 1987, R. Rittner and
J. B. Lambert, Eds., Unicamp Press, Ch. 2 pp. 17-44.

46.  Incommensurate Spinning Sidebands.  Vera, M.; Grutzner, J. B. Bull.
Magn. Reson. 1986, 8, 180-183.

47.  Grutzner, J. B., et al.,  Quimica Nova 1986, 9, 236-237, 254-255. 5
short summaries of references 42-46.

49.  The Continuously Rotated Cellular Reactor.  Grutzner, J. B.; Patrick,
E. A.; Pellechia, P.; Vera, M. J. Am. Chem. Soc. 1988, 110, 726-728.

50.  Magnetic Resonance Imaging of Couette and Taylor Vortex Flow.
Grutzner, J. B.; Vera, M. Proc. Xth Internat. Congress on Rheology, 1988,
1, 368-370.

51.  Vortex Stabilized Isoelectric Focusing Apparatus.  J.B. Grutzner and
P.J. Pellechia. U. S. Patent No. 4,900,421, 1990.

52.  The Synthesis of (+) Rubrynolide and Correction of its
Stereochemistry.  Taylor, S. K.; Hopkins, J. A.; Spangenberg, K. A.;
Grutzner, J. B.; McMillen, D. J. Org. Chem. 1991, 56, 5951-5955.

53.  Examination of Homogeneous Broadening in Solids via Rotationally
Synchronized Spin Echo NMR Spectroscopy.  Cowans, B. A.; Grutzner, J. B.;
J. Magn. Reson. 1993, A 105, 10-18.

54.  Carbon-13 NMR Relaxation Studies of Cycloalkylidene Bisphenols, Methyl
Ethers, and Simple Benzoate Esters in Solution:  Different Average
Correlation Times for Dipole-Dipole and Chemical Shift Anisotropy
Relaxation.  Lee, Y-H.; Allison, B. D.; Grutzner, J. B.  J. Phys Chem.
1994, 98, 1783-1790.

55.  Radical Bromination of Cyclohexene in CCl4 by Bromine:  Addition versus
Substitution.  McMillen, D. W.; Grutzner, J. B. J. Org. Chem., 1994, 59,
4516-4528.

56.  NMR Spinning Sidebands and Spin Echo Imaging of Fluid Flow.  Hopkins,
J. A.; Grutzner, J. B.  J. Magn. Reson., 1994, 111, 17-22.

57.  Conversion of Biomass to Ethanol: Isomerization of Xylose over HY
Zeolite.  C-Y. Lee, Wen, J.; Thomas, S. N.; Delgass, W. N.; Grutzner, J.
B.;Tsao, G. A. Appl. Biochem. and Biotech., 1994, 29-41.

58.  Geometry Considerations in Solvent Suppression Using B1-Gradients.
Hopkins, J. A.; Grutzner, J. B.; Canet, D.  J. Magn. Reson., 1995, 114,
98-100.

59.  NMR Velocity Mapping of Couette Flow Using Oscillating Magnetic Field
Gradients.  Hopkins, J. A.; Santini, R. E.; Grutzner, J. B. J. Magn.
Reson., 1995, 117, 153-160.

60.  Membrane Conformations and Their Relation to Cytotoxicity of Asimicin
and its Analogues.  Shimada, H.;  Grutzner, J. B.;  Kozlowski, J. F.;
Biochemistry – US  37:  (3) 854-866,  Jan. 20, 1998.

61.  Vegard's Rule Revisited in BaxPb1-x(NO3)2 by NMR and XRD1
Crundwell, G.A., Cowans, B.A., Hopkins, J.A., Grutzner, J.B., Kahr B.J.,
J. Solid State Chem., 145, 327-335, 1999.

62. 1H and 13C NMR Spectroscopy Analysis of a Series of Unsaturated
Hexenones and Heptenones.  Byrd, D.C., Steward, K.W., Grutzner, J.B.
Magn. Reson. Chem., 38, 479-481, 2000.

63. A New Mechanism for Spin-Lattice Relaxation of Heavy Nuclei in the
Solid State: 207Pb Relaxation in Lead Nitrate.  Grutzner, J.B., Stewart, K.W.,
Wasylishen, R.E., Lumsden, M.D., Dybowski, C., Beckmann, P. A.,
J. Am. Chem. Soc., 123,, 7094-7100, 2001.

64.  Robinlin: A novel Bioactive Homo-monoterpene from Robinia pseudacacia L.
(Fabaceae).  Tian, F., Chang C., Grutzner, J.B., Nichols, D.E., McLaughlin J.L.,
Bioorg. Med. Chem. Lett, 11, 2603-2606, 2001.

65.  Applications of NMR in Carbanion Chemistry. Grutzner, J.B., Encyclopedia
of Nuclear Magnetic Resonance, 9, 481-497, 2002.

66.  Dimerization and Trapping of Diazirinyl Radicals.  Thompson, R.A., Francisco,
J.S., Grutzner, J. B., Phys. Chem. Chem. Phys., 6, 756-765, 2004.

67.  Nuclear Magnetic Resonance (a) Principles.  Grutzner, J.B. Encyclopedia of
Analytical Science, Academic Press,  3358-3381, (2ndedit.) 2005.