Raftery Group, Purdue University Purdue University

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Solid-State NMR of Advanced Materials
  
We also study advanced or complex materials such as intrazeolite systems, atomic-sized semiconductors, and pharmaceutical compounds, in collaboration with a number of other research groups who speciallize in the synthesis of these materials. Such materials are challenging to study because of their complex and heterogeneous nature, and their spectra often consist of overlapping or broadened lines. This problem may be circumvented by spreading the spectra into more than one dimension, thereby increasing the resolution dramatically. In this way, solid-state NMR methods can probe the structure of an enormous variety of compounds and advanced materials and interrogate their dynamics in a broad range of time scales. Similar methods are used to gain information on the complex behavior of pharmaceutical compounds that are formulated in a variety of structures ranging from amorphous to polymorphic. Magnetic resonance methods are ideal to study the structural and dynamical behavior of such materials in order to characterize their viability as potential candidates for further development. [More-]