Wenthold Research Group

RECENT PUBLICATION LIST

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Professor Paul G. Wenthold
Group Member Pages

68.       Wenthold, P. G. Progress Toward the Systematic Decomposition of Benzene Angew. Chemie, 2005, in Press.

 

67.       Chacko, S. A., Krouse, I. H., Hammad, L. A., Wenthold, P. G. In Situ Generation of HCN for Mass Spectrometric Studies J. Am. Soc. Mass Spectrom., 2005, in Press.

 

66.       Chacko, S. A.; Wenthold, P. G. The Negative Ion Chemistry of Nitric Oxide in the Gas Phase Mass Spectrom. Rev., 2005, in Press.

 

65.       Schafman, B. S.; Wenthold, P. G. Organic Gas-Phase Ion Chemistry Annu. Rep. Prog. Chem. Sect. B. 2005, In Press

 

64.       Goebbert, D. J.; Hernandez, H.; Francisco, J.; Wenthold, P. G. The Binding Energy and Bonding in Dialane J. Am. Chem. Soc. 2005, 127, 11684-11689

63.       Krouse, I.H. and Wenthold, P.G. Fluorotrimethylsilane Affinities of Anionic Nucleophiles:  A Study of Fluoride-Induced Desilylation J. Am. Soc. Mass Spectrom. 2005, 16, 697-707.

 

62.       Liu, X.; Gross, M. L., Wenthold, P. G. Modeling the Dissociation of Protonated Butanedione.  The Enthalpy of Formation of Methylhydroxycarbene J. Phys. Chem. A, 2005, 109, 2183-2189.

 

61.       Munsch, T. E.; Wenthold, P. G. Organic Gas-Phase Ion Chemistry Annu. Rep. Prog. Chem. Sect. B., 2004, 100, 377-406

 

60.       Goebbert, D.J.; Wenthold, P.G. Water Dimer Proton Affinity from the Kinetic Method:  Dissociation Energy of the Water Dimer Eur. J. Mass Spectrom. 2004, 10, 837-845.

 

59.       Munsch, T. E., Slipchenko, L. V., Krylov, A. I., Wenthold, P. G.  Reactivity and Structure of 5-Dehydro-m-xylylene Anion J. Org. Chem. 2004, 69(17), 5735-5741.

 

58.       Krouse, I. H.; Wenthold, P. G.  Formation and Decomposition of Hydroxysiliconates in the Gas Phase Organometallics 2004, 23, 2573-2582.

 

57.       Slipchenko, L. V.; Munsch, T. E.; Wenthold, P. G.; Krylov, A.I.  5-Dehydro-1,3-quinodimethane:  A Hydrocarbon with an Open-Shell Doublet Ground State Angew. Chem. Int. Ed. 2004, 43, 742-745.

 

56.       Goebbert, D. J.; Liu, X.; Wenthold, P. G.  Reactions of Diacetylene Radical Cation with Ethylene J. Am. Soc. Mass Spectrom. 2004, 15, 114-120.

 

55.        Munsch, T.E.; Wenthold, P. G.  Organic Gas-Phase Ion Chemistry  Annu. Rep. Prog. Chem., Sect. B  2003, 420-446.

 

54.        Hammad, L. A.; Wenthold, P. G.  An Electron-Catalyzed Cope Cyclization.  The Structure of 2,5-Dicyano-1,5-Hexadiene Radical Anion in the Gas-Phase  J. Am. Chem. Soc. 2003, 125, 10796-10797.      Supplemental Material          (pdf)

53.        Krouse, I. H.; Wenthold, P. G.  Bond Dissociation Energy and Lewis Acidity of the Xenon Fluoride Cation  Inorg. Chem, 2003, 42, 4293-4298.  Supplemental Material            (pdf)

52.         Lardin, H. A.; Nash, J. J.; Wenthold, P. G.  Is the 1,3,5-tris(dehydro)benzene Triradical a Cyclopropenyl Radical Analogue?  J. Am. Chem. Soc., 2002, 124, 12612-12618.   Supplemental Material          (pdf)

51.         Hammad, L. A.; Ruane, P. H.; Kumar, N. A.; Toscano, J. P.; Wenthold, P. G.  The Energetics of Nitric Oxide Generation Upon Protonation of Diazeniumdiolates  Int. J. Mass Spectrom., 2003, 222, 269-279.  Supplemental Material          (pdf)     (html)

50.         Nimlos, M. R.; Davico, G.; Geise, C. M.; Wenthold, P. G.; Lineberger, W. C.; Blanksby, S. J.; Hadad, C. M.; Petersson, G. A.; Ellison, G. B.  Photoelectron Spectroscopy of HCCN- and HCNC- Reveals the Quasilinear Triplet Carbenes, HCCN and HCNC  J. Chem. Phys., 2002, 117, 4323-4339.

 

49.         Krouse, I. H.; Lardin, H. A.; Wenthold P. G.  Gas-Phase Ion Chemistry and Ion Thermochemistry of Phenyltrifluorosilane  Int. J. Mass Spectrom., 2003, 227, 303-314.  Supplemental Material          (pdf)     (html)

 

48.          Hu, H.; Wenthold P. G.  The Reaction of Butadiene Cation with Ethylene in the Gas Phase  J. Phys. Chem. A  2001, 106, 10550-10553.

 

47.          Poutsma, J. C.; Upshaw, S. D.; Squires R. R.; Wenthold, P. G.  The Absolute Heat of Formation and Singlet-Triplet Splitting for HCCN.  J. Phys. Chem. A  2002, 106, 1067-1073.

 

46.          Hammad, L. A.; Wenthold, P. G.  Triradical Thermochemistry from Collision-Induced Dissociation Threshold Measurements.  J. Am. Chem. Soc. 2001, 123, 12311-12317.

 

45.          Wenthold, P, G.  Oxidation/Reduction Reactions of Negative Ions in Encyclopedia of Mass Spectrometry 2001, in press. 

 

44.          Lardin, H. A.; Squires, R. R.; Wenthold, P. G.  Determination of the electron affinities of a- and b-naphthyl radicals using the kinetic method with full entropy analysis.  The C-H bond dissociation energies of naphthalene.  J. Mass Spectrom. 2001, 36, 607-615.

 

43.          Hu, H.; Wenthold, P. G.  The Structure of Ionized 1,5-Hexadiene in the Gas Phase.   J. Am. Soc. Mass Spectrom.  2001, 12, 840-845.

 

42.          Wenthold, P. G.; Liu, X.  Competing Mechanisms for Methyl Cation Loss from Protonated Acetaldehyde.   Int. J. Mass Spectrom. 2001, 207, 69-72.

 

41.          Wenthold, P. G.; Lipton, M. A.  A Density Functional Molecular Orbital Study of the C2 – C2 and C2 – C6 Cyclization Pathways of 1,2,4-Heptatrien-6-ynes.  The Role of Benzannulation.  J. Am. Chem. Soc. 2000, 122(38), 9265-9270.

 

40.          Hammad, L. A.; Wenthold, P. G.  Synthesis, Characterization, and Reactivity of the m-Xylylene Anion in the Gas-Phase.  The Enthalpy of Formation of m-Xylylene.  J. Am. Chem. Soc. 2000, 122, 11203-11211.

 

39.          Artau, A.; Nizzi, K. E.; Hill, B. T.; Sunderlin, L. S.; Wenthold, P. G.  Bond Dissociation Energy in Trifluoride Ion.  J. Am. Chem. Soc.  2000, 122, 10667-10670.

 

38.          Wenthold, P. G.  Determination of the Proton Affinities of Bromo- and Iodoacetonitrile Using the Kinetic Method with Full Entropy Analysis.  J. Am. Soc. Mass Spectrom. 2000, 11, 601-605.

 

37.          Wenthold, P. G.  Experimental Enthalpy of Formation of Isonitrile from Collision-Induced Dissociation Threshold Energy Measurements.  J. Phys. Chem. A 2000, 104, 5612-5616.

 

36.          Wenthold, P. G.  A Computational Study of the Electron Affinities of Substituted Cope Rearrangement Transition States.   J. Chem. Soc., Perkin Trans. 2  1999 2357-2363.

 

35.          Wenthold, P. G.  A Computational Study of the Hydride Affinities of Group I and Group II Metals.  Int. J. Mass Spectrom. 2000, 195/196, 319-325.

 

34.          Kim, J. B.; Wenthold, P. G.; Lineberger, W. C.  Ultraviolet Photoelectron Spectroscopy of o, m, and p-Halobenzyl Anions.  J. Phys. Chem. A, 1999, 103(50), 10833-10841.

 

33.          Wenthold, P. G.; Hu, J.;  Squires, R. R.; Lineberger, W. C.  Photoelectron Spectroscopy of the Trimethylenemethane Negative Ion.  J. Am. Soc. Mass Spectrom.  1999, 10(9), 800-809.

 

32.          Wenthold, P. G.; Lineberger, W. C.  Negative Ion Photoelectron Spectroscopy Studies of Organic Reactive Intermediates.  Acc. Chem. Res. 1999, 32(7), 597-604.

 

31.          Wenthold, P. G.  A Computational Study of the Electron Affinity of Silene.  Chem. Phys. Lett. 1998, 297, 445-450.

 

30.          Clifford, E. P.; Wenthold, P. G.; Gareyev, R.; Lineberger, W. C.; DePuy, C. H.; Bierbaum, V. M.; Ellison, G. B. Photoelectron Spectroscopy Gas Phase Acidity, and Thermochemistry of tert-Butyl Hydroperoxide: Mechanisms for the Rearrangement of Peroxyl Radicals.  J. Chem. Phys. 1998, 109(23), 10293-10310.

 

29.          Wenthold, P. G.; Hu, J.; Squires, R. R.  Gas-Phase Reactions of the Benzyne Negative Ion.  J. Mass Spectrom.  1998, 33, 796-802.

 

28.          Clifford, E. P.; Wenthold, P. G.; Lineberger, W. C.; Petersson, G. A.; Broadus, K. M.; Kass, S. R.; Kato, S.; DePuy, C. H.; Bierbaum, V. M.; Ellison, G. B.  Properties of Diazocarbene [CNN] and the Diazomethyl Radical [HCNN] via Ion Chemistry and Spectroscopy.  J. Phys. Chem. A. 1998, 102, 7100-7112.

 

27.          Wenthold, P. G.; Hu, J.; Hill, B. T.; Squires, R. R.  Gas-Phase Negative Ion Chemistry of Molecular Fluorine.  Synthesis of Distonic Radical Anions and Related Species.   Int. J. Mass Spectrom. Ion Processes 1998, 179/180, 173-183.

 

26.          Wenthold P. G.; Squires, R. R.; Lineberger, W. C.  Ultraviolet Photoelectron Spectroscopy of the o, m, and p-Benzyne Negative Ions.  Electron Affinities and Singlet-Triplet Splittings for o, m, and p-Benzyne.  J. Am. Chem. Soc. 1998, 120, 5279-5290.

 

25.          Clifford, E. P. ; Wenthold, P. G.; Lineberger, W. C.; Ellison, G. B.; Wang, C. X.; Grabowski, J. J.; Vila, F.; Jordan, K. D.  Properties of Tetramethyleneethane (TME) as Revealed by Ion Chemistry and Ion Photoelectron Spectroscopy.  J. Chem Soc., Perkin Trans. 2  1998  1015-1022.

 

24.          Wenthold, P. G.; Squires, R. R.  Gas-Phase Acidities of o, m, and p-Dehydrobenzoic Acid Radicals.  Determination of the Substituent Constants for a Phenyl Radical Site.  Int. J. Mass Spectrom. Ion Processes 1998, 175, 215-224.

 

23.          Kim, J. B.; Wenthold, P. G.; Lineberger, W. C.  Photoelectron Spectroscopy of OH- (N2O)n=1-5.  J. Chem. Phys. 1998, 108(3), 830-837.

 

22.          Wenthold, P. G.; Lineberger, W.C.  Dehydrocyclooctatetraene.  Photoelectron Spectroscopy of the C8H6 Anion.  J. Am. Chem. Soc. 1997, 119(33), 7772-7777.

 

21.          Kato, S.; Lee, H. S.; Gareyev, R.; Wenthold, P. G.; Lineberger, W. C.; DePuy, C. H.; Bierbaum, V. M.  Experimental and Computational Studies of the Structures and Energetics of Cyclooctatetraene and Its Derivatives.  J. Am. Chem. Soc. (1997), 119(33), 7863-7864.

 

20.          Wenthold, P. G.; Jonas, K. -L.; Lineberger, W. C.  Ultraviolet Photoelectron Spectroscopy of the Chromium Dioxide Negative Ion.  J. Chem. Phys. 1997, 106(23), 9961-9962.

 

19.          Clifford, E. P.; Wenthold, P. G.; Lineberger, W. C.; Petersson, G. A.; Ellison, G. B.  Photoelectron Spectroscopy of the NCN- and HNCN- Ions.  J. Phys. Chem. A 1997, 101(24), 4338-4345.

 

18.          Wenthold, P. G.; Kim, J. B.; Jonas, K. -L.; Lineberger, W. C.  An Experimental and Computational Study of the Electron Affinity of Boron Oxide.  J. Phys. Chem. A 1997, 101(24), 4472-4474.

 

17.          Wenthold, P. G.; Kim, J. B.; Lineberger, W. C.  Photoelectron Spectroscopy of m-Xylylene Anion.  J. Am. Chem. Soc. 1997, 119(6), 1354-1359.

 

16.          Wenthold, P. G.; Gunion, R. F.; Lineberger, W. C.  Ultraviolet Negative-Ion Photoelectron Spectroscopy of the Chromium Oxide Negative Ion.  Chem. Phys. Lett. 1996, 258(1,2), 101-106.

 

15.          Wenthold, P. G.; Hrovat, D. A.; Borden, W. T.; Lineberger, W. C. Transition-State Spectroscopy of Cyclooctatetraene.  Science (Washington, D.C.) 1996, 272(5267), 1456-1459.

 

14.          Gunion, R. F.; Karney, W.; Wenthold, P. G.; Borden, W. T.; Lineberger, W.C.  Ultraviolet Photoelectron Spectroscopy of Some C7H7- Isomers: Quadricyclanide, Norbornadienide, Cycloheptatrienide, and 1,6-Heptadiynide.  J. Am. Chem. Soc. 1996, 118(21), 5074-5082.

 

13.          Wenthold, P. G.; Polak, M. L.; Lineberger, W.C.  Photoelectron Spectroscopy of the Allyl and 2-Methylallyl Anions.  J. Phys. Chem. 1996, 100(17), 6920-6926.

 

12.          Wenthold, P. G.; Hu, J.; Squires, R. R.; Lineberger, W. C.  Photoelectron Spectroscopy of the Trimethylenemethane Negative Ion.  The Singlet-Triplet Splitting of Trimethylenemethane.   J. Am. Chem. Soc. 1996, 118(2), 475-476.

 

11.          Wenthold, P. G.; Hu, J.; Squires, R. R.  o, m, and p-Benzyne Negative Ions in the Gas Phase: Synthesis, Authentication, and Thermochemistry.  J. Am. Chem. Soc. 1996, 118(47), 11865-11871.

 

10.          Wenthold, P. G.; Squires, R. R.  Bond Dissociation Energies of F2- and HF2-.  A Gas-Phase Experimental and G2 Theoretical Study.  J. Phys. Chem. 1995, 99(7), 2002-2005.

 

9.            Wenthold, P. G.; Squires, R. R.  Determination of the Gas-Phase Acidities of Halogen-Substituted Aromatic Compounds Using the Silane-Cleavage Method.  J. Mass Spectrom. 1995, 30(1), 17-24.

 

8.            Wenthold, P. G.; Squires, R. R.  Gas-Phase Properties and Reactivity of the Acetate Radical Anion.  Determination of the C-H Bond Strengths in Acetic Acid and Acetate Ion.  J. Am. Chem. Soc. 1994, 116(26), 11890-11897.

 

7.            Wenthold, P. G.; Hu, J.; Squires, R. R.  Regioselective Synthesis of Biradical Negative Ions in the Gas Phase.  Generation of Trimethylenemethane, m-Benzyne, and p-Benzyne Anions.  J. Am. Chem. Soc. 1994, 116(15), 6961-6962.

 

6.            Wenthold, P. G.; Wierschke, S. G.; Nash, J. J.; Squires, R. R.  Experimental and Theoretical Studies of the Mechanism and Thermochemistry of Formation of a,n- Dehydrotoluene Biradicals from Gas-Phase Halide Elimination Reactions.  J. Am. Chem. Soc. 1994, 116(16), 7378-7392.

 

5.            Wenthold, P. G.; Squires, R. R.  Biradical Thermochemistry from Collision-Induced Dissociation Threshold Energy Measurements.  Absolute Heats of Formation of ortho-, meta-, and para-Benzyne.  J. Am. Chem. Soc. 1994, 116(14), 6401-6412.

 

4.            Marinelli, P. J.; Paulino, J. A.; Sunderlin, L. S.; Wenthold, P. G.; Poutsma, J. C.; Squires, R. R.  A Tandem Selected Ion Flow Tube-Triple Quadrupole Instrument.  Int. J. Mass Spectrom. Ion Processes 1994, 130(1-2), 89-105.

 

3.            Wenthold, P. G.; Wierschke, S. G.; Nash, J. J.; Squires, R. R. a,3-Dehydrotoluene: Experimental and Theoretical Evidence for a Singlet Ground State.  J. Am. Chem. Soc. 1993, 115(26), 12611-12612.

 

2.            Wenthold, P. G.; Paulino, J. A.; Squires, R. R.  The Absolute Heats of Formation of o, m, and p-Benzyne.  J. Am. Chem. Soc. 1991, 113(19), 7414-7415.

 

1.            Gassman, P. G.; Ray, J. A.; Wenthold, P. G.; Mickelson, J. W.  Synthesis of Perfluoroalkylated Indenes.  J. Org. Chem. 1991, 56, 5143-5146.