Philip L. Fuchs

All Publications

1. A Bicyclo [2.1.0] Pentane Phenonium Ion
H.W. Whitlock, Jr., P.L. Fuchs
Tetrahedron Lett. 1968, 1453-1456.
2. An Improved Aldehyde Synthesis from 1,3-Dithianes
E. Vedejs, P.L. Fuchs
J. Org. Chem. 1971, 36, 366-368
3. Olefin Inversion by the Phosphorus Betaine Method
E. Vedejs, P.L. Fuchs
J. Am. Chem. Soc. 1971, 93, 4070-4072
4. Homoconjugate Addition of Organocopper Reagents to Cyclopropanes and Its Application to the Synthesis of Prostanoids
E.J. Corey, P.L. Fuchs
J. Am. Chem. Soc. 1972, 94, 4014-4015
5. A Synthesis Method for the Formyl to Ethynyl Conversion
E.J. Corey, P.L. Fuchs
Tetrahedron Lett. 1972, 3769-3772
6. Inversion of Acyclic Olefins by the Phosphorus Betaine Method; Scope and Limitations
E. Vedejs, P.L. Fuchs
J. Am. Chem. Soc. 1973, 95, 822-825
7. Betaines Derived from Cycloheptane- and Cyclooctane-Oxides: Preparation of Trans-Cyclooctene Derivatives
E. Vedejs, K.A.J. Snoble, P.L. Fuchs
J. Org. Chem. 1973, 38, 1178-1183
8. Wittig Reactions of Allyl Ylides: Substitution of the gamma-Position
E. Vedejs, J.P. Bershas, P.L. Fuchs
J. Org. Chem. 1973, 38, 3625-3627
9. Carboethoxycyclopropyl Triphenylphosphonium Fluroborate. A Reagent for the Facile Cycloalkenylation of Carbonyl Groups
P.L. Fuchs
J. Am. Chem. Soc. 1974, 96, 1607-1609
10. Trans-1-butadienyltriphenylphosphonium Bromide. A Reagent for the 1,3-Cyclohexadienylation of Carbonyl Groups
P.L. Fuchs
Tetrahedron Lett. 1974, 4055-4058
11. alpha-Arylation of Carbonyl Groups. Utilization of the p-Toluenesulfonylazo Olefin Functional Group as an Enolonium Synthon
C.E. Sacks, P.L. Fuchs
J. Am. Chem. Soc.1975, 97, 7372-7374 [Synthetic Utilization of the Imine Moiety 1]
12. Carbonyl Regeneration from p-Toluenesulfonylhydrazones
C.E. Sacks, P.L. Fuchs
Synthesis 1976, 456-458 [Synthetic Utilization of the Imine Moiety 2]
13. alpha-Arylation of alpha, beta-Unsaturated Ketones: Utilization of the alpha-Epoxytosylhydrazone Functional Group as a D2-Enonium Synthon
P.L. Fuchs
J. Org. Chem. 1976, 41, 2935-2937 [Synthetic Utilization of the Imine Moiety 3]
14. alpha'-Functionalization of beta, gamma-Unsaturated Cyclohexenones. Utilization of Silyl Enol Ethers Produced from the Lithium/Ammonia Reduction of Silyl Aryl Ethers
R.E. Donaldson, P.L. Fuchs
J. Org. Chem. 1977, 42, 2032-2034
15. Rapid and Unequivocal Determination of Syn-Anti Stereochemistry for Toluenesulfonylhydrazones and Other Imine Derivatives Via Carbon NMR Spectroscopy: A Synthetic Adjunct
C.A. Bunnell, P.L. Fuchs
J. Org. Chem. 1977, 42, 2614-2617 [Synthetic Utilization of the Imine Moiety ]
16. Hydrogentriphenylphosphonium Tetrafluoroborate: A Reagent for Conversion of Thiodienes to Thioallylphosphonium Tetrafluoroborates
D.A. Clark, P.L. Fuchs
Synthesis 1977, 628-630
17. Synthesis of beta, gamma-Unsaturated Esters. Direct Generation of Ester Dienolates from beta-Keto Ester Tosylhydrazone Trianions
C.A. Bunnell, P.L. Fuchs
J. Am. Chem. Soc. 1977, 99, 5184-5187 [Synthetic Utilization of the Imine Moiety 5]
18. Chlorosulfenylation-Dehydrochlorination Reactions. New and Improved Methodology for the Synthesis of Unsaturated Aryl Sulfides and Aryl Sulfones
P.B. Hopkins, P.L. Fuchs
J. Org. Chem. 1978, 43, 1208-1217
19. A Versatile and Expedient Synthesis of alpha,beta-Unsaturated Ketones. Utilization of the beta-Epoxy Sulfone Functional Group as the Enone Progenitor
P.C. Conrad, P.L. Fuchs
J. Am. Chem. Soc. 1978, 100, 346-348 [Syntheses Via Vinyl Sulfones 1]
20. Intramolecular Carbon Alkylation of Oxime Anions. Stereospecific Generation and Rearrangement of Nitrosocyclopropanes and Nitrosocyclobutanes
D.A. Clark, C.A. Bunnell, P.L. Fuchs
J. Am. Chem. Soc. 1978, 100, 7777-7779 [Synthetic Utilization of the Imine Moiety 6]
21. Conjugate-Addition Reactions of Organometallic Reagents to g-Oxygenated-alpha,beta-Unsaturated Sulfones: Control of Stereochemistry at the beta-Position
J.C. Saddler, P.C. Conrad, P.L. Fuchs
Tetrahedron Lett. 1978, 5079-5082 [Syntheses Via Vinyl Sulfones 2]
22. Macrocycle Synthesis Via Enolate-Assisted, Intraannular 1,4-Fragmentation Reactions
D.A. Clark, P.L. Fuchs
J. Am. Chem. Soc. 1979, 101, 3567-3576 [Cytochalasin Support Studies 1]
23. "Carbon-13 NMR Based Organic Spectral Problems,"
P.L. Fuchs, C.A. Bunnell
John-Wiley, New York, 1979
24. Synthesis of a Model for the BCE Ring System of Bruceantin. A Caveat on the Cyclohexene to Trans Diaxial Diol Conversion
O.D. Dailey, Jr., P.L. Fuchs
J. Org. Chem. 1980, 45, 216-236 [Bruceantin Support Studies 1]
25. Conjugate-Addition Reactions of Highly Functionalized Aryl Lithium Reagents to gamma-Silyloxy-alpha,beta-Unsaturated Sulfones: Consequences of the Structure of the Sulfone Moiety
D.L. Barton, P.C. Conrad, P.L. Fuchs
Tetrahedron Lett. 1980, 21, 1811-1814 [Syntheses Via Vinyl Sulfones 3]
26. Chiral and Stereochemical Control Via an Intramolecular Diels-Alder Reaction of a Z-diene
S.G. Pyne, M.J. Hensel, S.R. Byrn, A.T. McKenzie, P.L. Fuchs
J. Am. Chem. Soc. 1980, 102, 5960-5962 [Cytochalasin Support Studies 2]
27. Six-Membered Ring Annulation Via a Conjugate-Addition/Alkylation Sequence Using Functionalized Aryllithium Reagents and Vinyl Sulfones
J. Ponton, P. Helquist, P.C. Conrad, P.L. Fuchs
J. Org. Chem. 1981, 46, 118-122 [Syntheses Via Vinyl Sulfones 4]
28. A Triply Convergent Total Synthesis of l-(-)-Prostaglandin E2
R.E. Donaldson, P.L. Fuchs
J. Am. Chem. Soc. 1981, 103, 2108-2110 [Syntheses Via Vinyl Sulfones 5]
29. Enantioconvergent Syntheses of Two Classes of Chiral Cyclopentenyl Sulfone Synthons
J.C. Saddler, R.E. Donaldson, P.L. Fuchs
J. Am. Chem. Soc. 1981, 103, 2110-2112 [Syntheses Via Vinyl Sulfones 6]
30. Syntheses Via Vinyl Sulfones 7. Enantiospecific Syntheses of gamma-Substituted Enones: Organometallic SN2' Conjugate-Addition Reactions of Epoxy Vinyl Sulfones
J.C. Saddler, P.L. Fuchs
J. Am. Chem. Soc. 1981, 103, 2112-2114.
31. PULSAR: A Personalized Microcomputer-Based System for Keyword Search and Retrieval of Literature Information
S.F. Smith, W.L. Jorgensen, P.L. Fuchs
J. Chem. Info. Comp. Sci. 1981, 21, 209-213
32. Synthesis of gamma-Hydroxy Enones Via Persulfate Oxidation of Dienyl Ethers
S.N. Suryawanshi, P.L. Fuchs
Tetrahedron Lett. 1981, 22, 4201-4204 [Bruceantin Support Studies 2]
33. The C14-C19 Subunit of Cytochalasin C. Intramolecular 2+2 Photochemical Cycloaddition of Vinyl Sulfones
A.K. Musser, P.L. Fuchs
J. Org. Chem. 1982, 47, 3121-3131 [Cytochalasin Support Studies 3, Syntheses Via Vinyl Sulfones 8]
34. Chiral and Stereochemical Control Via Intramolecular Diels-Alder Reactions of Z-Dienes
S.G. Pyne, M.J. Hensel, P.L. Fuchs
J. Am. Chem. Soc. 1982, 104, 5719-5728 [Cytochalasin Support Studies 4]
35. Conjugate-Addition of beta-Keto Ester Dianions to Vinyl Sulfones: A New Procedure for Seven-Ring Annulation. Synthesis of Chiral Cytochalasin C Intermediate Via an Intramolecular Diels-Alder Reaction of a Chiral Z Diene
S.G. Pyne, D.C. Spellmeyer, S. Chen, P.L. Fuchs
J. Am. Chem. Soc. 1982, 104, 5728-5740 [Cytochalasin Support Studies 5, Syntheses Via Vinyl Sulfones 9]
36. Conjugate-Addition of Moderately Soft Anions to a Vinyl Sulfone
P.R. Hamann, P.L. Fuchs
J. Org. Chem. 1983, 48, 914-916 [Syntheses Via Vinyl Sulfones 10]
37. The Robinson Transposition Reaction. Conjugate-Addition/Intramolecular Wittig Reactions of Enolates with [3-(Phenylthio)-1,3-butadienyl]triphenylphosphonium Chloride
R.J. Pariza, P.L. Fuchs
J. Org. Chem. 1983, 48, 2304-2306 [Bruceantin Support Studies 3]
38. An Improved Procedure for the Synthesis of 4-Oxopimelate-Derived Materials. R.J. Pariza, F. Kuo, P.L. Fuchs Syn. Comm. 1983, 13, 243-254. [Bruceantin Support Studies 4]
39. Rapid Access to a Highly Functionalized Tricyclic Bruceantin Intermediate
R.J. Pariza, P.L. Fuchs
J. Org. Chem. 1983, 48, 2306-2308 [Bruceantin Support Studies 5]
40. Triply-Convergent Total Synthesis of l-(-) Prostaglandin E2
R.E. Donaldson, J.C. Saddler, A.T. McKenzie, S. Byrn, P.L. Fuchs
J. Org. Chem. 1983, 48, 2167-2188 [Syntheses Via Vinyl Sulfones 11]
41. CRIMP: A Microcomputer-Based System for Inventory and Management of Chemical Resources
S.F. Smith, P.L. Fuchs
Laboratory Microcomputer 1984, 2, 15-20
42. Cesium Fluoride-Mediated Intramolecular Conjugate-Additions of alpha-Sulfonyl Esters to Enones
S.N. Suryawanshi, P.L. Fuchs
Tetrahedron Lett. 1984, 25, 27-30 [Bruceantin Support Studies 6]
43. Torsional Effects in the Baeyer-Villiger Oxidation
S.N. Suryawanshi, C.J. Swenson, W.L. Jorgensen, P.L. Fuchs
Tetrahedron Lett. 1984, 25, 1859-1862 [Bruceantin Support Studies 7]
44. Tandem Intramolecular Conjugate-Addition/Intramolecular Alkylation Reactions of beta-Substituted Vinyl Sulfones
P.R. Hamann, J.E. Toth, P.L. Fuchs
J. Org. Chem. 1984, 49, 3865-3867 [Morphine Support Studies 1, Syntheses Via Vinyl Sulfones 12]
45. Robotic Orchestration of Organic Reactions: Yield Optimization Via an Automated System with Operator-Specified Reaction Sequences
A.R. Frisbee, M.H. Nantz, G.W. Kramer, P.L. Fuchs
J. Amer. Chem. Soc. 1984, 106, 7143-7145 [PASS 1]
46. Robotic Optimization of Organic Reactions: Phase I
A.R. Frisbee, P.L. Fuchs, G.W. Kramer
Advances In Laboratory Automation Robotics 1984, 47-59 [PASS 2]
47. Synthesis of a Chiral Bicyclo [4.1.0] Allylic Nitrile Via Reductive Cyclization of a Dienyl Nitrile
T.F. Braish, P.L. Fuchs
Syn. Comm. 1985, 15, 549-567
48. Studies Related to the Robinson Transposition Reaction
R.J. Pariza, P.L. Fuchs
J. Org. Chem. 1985, 50, 4252-4266 [Bruceantin Support Studies 8]
49. Stereoselective, Chemodirected Formal SN2' Addition of Organometallic Reagents to beta'-Amino Cyclopentenyl Sulfone Derivatives
D.K. Hutchinson, P.L. Fuchs
J. Am. Chem. Soc. 1985, 107, 6137-6138 [Syntheses Via Vinyl Sulfones 13]
50. Robotic Automation in Organic Synthesis
G.W. Kramer, P.L. Fuchs
Advances In Laboratory Automation Robotics 1985, 417-429 [PASS 3]
51. External Control of the Zymark Robot
A.R. Frisbee, D.A. Lantrip, P.L. Fuchs, G.W. Kramer
Zymark Laboratory Automation Newsletter 1985, 2, 3-4 [PASS 4]
52. KH/18-Crown-6: A Powerful Base for the Protection of Hindered Alcohols with t-Butyldimethylsilylchloride
T.F. Braish, P.L. Fuchs
Syn. Comm. 1986, 16, 111-115
53. Desulfurization of a-Sulfenylated Allyl Nitriles Using an Amine-Deactivated Palladium [0] Catalyst
T.F. Braish, P.L. Fuchs
Syn. Comm. 1986, 16, 785-793
54. A Highly Selective Synthesis of a Chiral gamma-Amino Trisubstituted Z-Vinyl Ester
M.J. Hensel, P.L. Fuchs
Syn. Comm. 1986, 16, 1285-1295 [Cytochalasin Support Studies 6]
55. An Intramolecular Diels-Alder Reaction of a Z-Diene. Generation of the Chiral Isoindolone Nucleus of Cytochalasin C
M.J. Hensel, J.T. Palmer, P.L. Fuchs
Syn. Comm. 1986, 16, 1297-1314 [Cytochalasin Support Studies 7]
56. Synthesis And Facile One-Pot Aldol/Elimination/Diels-Alder Reaction of beta-Keto-Z-Dienylamides as Cytochalasin C Intermediates
J.T. Palmer, K.S. Learn, P.L. Fuchs
Syn. Comm. 1986, 16, 1315-1333 [Cytochalasin Support Studies 8, Syntheses Via Vinyl Sulfones 17]
57. Use of an Axial a-Face Control Element in Intramolecular Conjugate Additions: Synthesis of an ABCD Tetracyclic Bruceantin Precursor
S.N. Suryawanshi, P.L. Fuchs
J. Org. Chem. 1986, 51, 902-921 [Bruceantin Support Studies 9]
58. Formation of the Neopinone/Codeinone Ring System Via Intramolecular 1,6 Addition of an Amino Moiety to a Dienyl Ketone
J.E. Toth, P.L. Fuchs
J. Org. Chem. 1986, 51, 2594-2596 [Morphine Support Studies 2]
59. Amine-Directed Addition of Cuprate Reagents to Cyclopentenyl Sulfones
D.K. Hutchinson, S.A. Hardinger, P.L. Fuchs
Tetrahedron Lett. 1986, 27, 1425-1428 [Syntheses Via Vinyl Sulfones 15]
60. On the Chemistry of Diallyl Cuprate
D.K. Hutchinson, P.L. Fuchs
Tetrahedron Lett. 1986, 27, 1429-1432 [Syntheses Via Vinyl Sulfones 16]
61. Multiply-Convergent Syntheses Via Conjugate-Addition Reactions to Cycloalkenyl Sulfones
T.F. Braish, P.L. Fuchs
Chem. Rev. 1986, 86, 903-917 [Syntheses Via Vinyl Sulfones 25]
62. Use of 1-Penten-3-one-4-phosphonate as a Kinetic Ethyl Vinyl Ketone Equivalent in the Robinson Annulation Reaction
F. Kuo, P.L. Fuchs
Syn. Comm. 1986, 16, 1745-1759 [Bruceantin Support Studies 11]
63. Automation in Organic Synthesis: In Search of the Electronic Chemist
G.W. Kramer, P.L. Fuchs
Byte 1986, 263-284 [PASS 5]
64. Robotic Automation in Organic Synthesis
G.W. Kramer, P.L. Fuchs
Advances In Laboratory Automation Robotics 1986, 361-372 [PASS 6]
65. Rapid Access to a Series of Highly Functionalized alpha,beta-Unsaturated Cyclopentenones. A Cavaet on Amino Spirocyclization
P.C. Conrad, P.L. Kwiatkowski, P.L. Fuchs
J. Org. Chem. 1987, 52, 586-591 [Syntheses Via Vinyl Sulfones 18]
66. Use of an Axial beta-Face Thiomethyl Control Element in Intramolecular Conjugate Additions. Synthesis of a Tricyclic Bruceantin Precursor
D.M. Hedstrand, A. McKenzie, S. Byrn, P.L. Fuchs
J. Org. Chem. 1987, 52, 592-598 [Bruceantin Support Studies 10]
67. A Self-Immolative Strategy for 1,2 Elimination of Homoallyl Sulfones to 1,3 Dienes
X. Radisson, P.L. Kwiatkowski, P.L. Fuchs
Syn. Comm. 1987, 17, 39-53 [Syntheses Via Vinyl Sulfones 19]
68. Efficient 4 + 1 Syntheses of Highly Functionalized Cyclopentenes
X. Radisson, M.H. Nantz, P.L. Fuchs
Syn. Comm. 1987, 17, 55-69 [Syntheses Via Vinyl Sulfones 20]
69. Total Synthesis of dl-Morphine
J.E. Toth, P.L. Fuchs
J. Org. Chem. 1987, 52, 473-475 [Syntheses Via Vinyl Sulfones 21, Morphine Support Studies 3]
70. A Chemodirected, Triply Convergent Total Synthesis of d-(+)-Carbacyclin
D.K. Hutchinson, P.L. Fuchs
J. Amer. Chem. Soc. 1987, 109, 4755-4756 [Syntheses Via Vinyl Sulfones 22]
71. Synthesis of a Pentacyclic ABCDE Bruceantin Intermediate
F. Kuo, P.L. Fuchs
J. Amer. Chem. Soc. 1987, 109, 1122-1128 [Bruceantin Support Studies 12]
72. An Efficient Method for Conversion of Carboxylic Acid Derivatives to Allylsilanes
M.B. Anderson, P.L. Fuchs
Syn. Comm. 1987, 17, 621-635
73. Addition of Organometallic Reagents to Cyclooctenyl Sulfones
S.A. Hardinger, P.L. Fuchs
J. Org. Chem. 1987, 52, 2739-2749 [Syntheses Via Vinyl Sulfones 23]
74. Amelioration of the Conjugate-Addition Chemistry of alpha-Alkoxy Copper Reagents: Application to the Stereospecific Synthesis of C-Glycosides
D.K. Hutchinson, P.L. Fuchs
J. Amer. Chem. Soc. 1987, 109, 4930-4939 [Syntheses Via Vinyl Sulfones 24]
75. Cycloaromatization Reactions of Methyl 4-Carbomethoxy-5-methoxy-penta-2,4-dienoate
M.H. Nantz, P.L. Fuchs
Syn. Comm. 1987, 17, 761-771
76. Efficient Generation and Use of 3-Carboalkoxycyclopentadienone as a Diels-Alder Dienophile
M.H. Nantz, P.L. Fuchs
J. Org. Chem. 1987, 52, 5298-5299 [Bruceantin Support Studies 13]
77. Transferring Text Information to a Computer Using the Zymate Printer Interface
D.A. Lantrip, A.R. Frisbee, P.L. Fuchs, G.W. Kramer
Zymark Laboratory Automation Newsletter 1987, 4, 8-9 [PASS 7]
78. Error Minimization in Robotic Syringing Techniques
M.J. Trueblood, A.R. Frisbee, D.A. Lantrip, P.L. Fuchs, G.W. Kramer
Zymark Laboratory Automation Newsletter 1987, 4, 5-6 [PASS 8]
79. Improving Zymate Syringe Hand Reliability in Applications Requiring Septum Penetration
A.R. Frisbee, P.L. Fuchs , G.W. Kramer
Zymark Laboratory Automation Newsletter 1987, 4, 7-9 [PASS 9]
80. Robotic Automation of Some Common Organic Laboratory Techniques
G.W. Kramer, P.L. Fuchs
Advances in Laboratory Automation Robotics 1987, 339-359 [PASS 10]
81. Evidence for Competitive Intramolecular Trimethylsilyl Rearrangement to Oxygen and Sulfur in beta-Trimethylsilylethylthiolesters
K.V. Wood, A.P. Rothwell, M.B. Anderson, P.L. Fuchs
Rapid Communications in Mass Spectrometry 1988, 2, 38-40
82. A Facile Synthesis of Unsymmetrical Thiolsulfonates Via Sulfonylation of Mercaptans
M.G. Ranasinghe, P.L. Fuchs
Syn. Comm. 1988, 18, 227-232 [Cytochalasin Support Studies 9]
83. Synthesis and Alkylation of Vinylsulfinic Acids Via Fluoride Cleavage of beta-Trimethylsilylethyl Vinyl Sulfones
J.T. Palmer, P.L. Fuchs
Syn. Comm. 1988, 18, 233-245 [Syntheses Via Vinyl Sulfones 26, Cytochalasin Support Studies 10]
84. Total Synthesis dl-Cephalotaxine. The First Example of an Intramolecular 4 + 2 Cycloaddition where the Dienophile has been Delivered from the Face Opposite to the Tethering Moiety
T.P. Burkholder, P.L. Fuchs
J. Amer. Chem. Soc. 1988, 110, 2341-2342 [Syntheses Via Vinyl Sulfones 27]
85. Regiospecific Quassinoidal A-Ring Synthesis Via an Olefin Oxidation Strategy
S.V. Govindan, P.L. Fuchs
J. Org. Chem. 1988, 53, 2593-2597 [Bruceantin Support Studies 14]
86. Nucleophilic and Electrophilic Mercaptanylations Via 2-(trimethylsilyl)Ethanethiol-derived Reagents
M.B. Anderson, M.G. Ranasinghe, J.T. Palmer, P.L. Fuchs
J. Org. Chem. 1988, 53, 3125-3127 [Cytochalasin Support Studies 11]
87. Seven-Ring Annulation: A Linch-Pin Approach to a Tetracyclic Precursor of the Lathrane Diterpenes
T.F. Braish, J.C. Saddler, P.L Fuchs
J. Org. Chem. 1988, 53, 3647-3658 [Syntheses Via Vinyl Sulfones 28]
88. Studies Culminating in the Total Synthesis of (dl)-Morphine
J.E. Toth, P.R. Hamann, P.L. Fuchs
J. Org. Chem. 1988, 53, 4694-4708 [Syntheses Via Vinyl Sulfones 29]
89. RS-232 Remote Control of Zymate Peripheral Devices with an External Computer
G.J. Sabadosa, P.L. Fuchs, W. Buote, G.W. Kramer
Laboratory Robotics and Automation 1988, 1, 21-33 [PASS 11]
90. Ramberg-Bäcklund Syntheses and Chemodirected Annulations of Exocyclic Allylsilanes
M.G. Ranasinghe, P.L. Fuchs
J. Amer. Chem. Soc. 1989, 111, 779-782 [Syntheses Via Vinyl Sulfones 36, Cytochalasin Support Studies 12]
91. SN2' Additions of Cuprates to Sulfone and Ester-Polarized Cyclopentenylic Systems
Y. Pan, D.K. Hutchinson, M.H. Nantz, P.L. Fuchs
Tetrahedron 1989, 45, 467-478 [Syntheses Via Vinyl Sulfones 34]
92. SN2' Addition of Organometallic Reagents to b'-Amino Cyclohexenyl Sulfone Derivatives
Y. Pan, S.A. Hardinger, P.L. Fuchs
Syn. Comm. 1989, 19, 403-416 [Syntheses Via Vinyl Sulfones 35]
93. Synthesis of Fluorinated Dienylic Stannanes Via the Wadsworth-Emmons Reaction
R.A. Berglund, P.L. Fuchs
Syn. Comm. 1989, 19, 1965-1980
94. Chemistry 261-2 Lecture Notes
P. L. Fuchs
1989, Stipes Publishing Co., 10-12 Chester Street, Champaign, IL 61820
95. Controlling the Purdue Automated Synthesis System
D.A. Lantrip, P.L. Fuchs, G.W. Kramer
Advances in Laboratory Automation Robotics 1989, 115-137 [PASS 12]
96. A Robotic Interface for the HP 1090M High Performance Liquid Chromatograph
C.P. Sears III, P.L. Fuchs, G.W. Kramer
LC-GC 1989, 7, 263-65 [PASS 13]
97. A Simple, Automated Device for the Precise Addition of Liquids
G.W. Kramer, J.M. Hanquier, A.R. Frisbee, P.L. Fuchs
J. Autom. Chem. 1989, 11, 1-14 [PASS 14]
98. Develop Reactions Automatically
G.W. Kramer, P.L. Fuchs
Chemtech 1989, 19, 682-689 [PASS 15]
99. TRAIN: A General Purpose Sample Transport Mechanism for Automated Systems
C.P. Sears III, P.L. Fuchs, G.W. Kramer
Laboratory Robotics and Automation 1989, 1, 257-264 [PASS 16]
100. The Importance of Ensuring Sample Homogeneity in Automated Systems
G.J. Sabadosa, P.L. Fuchs, G.W. Kramer
Laboratory Robotics and Automation 1989, 1, 265-267 [PASS 17]
101. Testing the Purdue Automated Synthesis System
G.W. Kramer, D.A. Lantrip, C.P. Sears III, G.J. Sabadosa, P.L. Fuchs
International Symposium on Laboratory Robotics 1989, 409-434 [PASS 18]
102. alpha-Silyl Sulfones as Latent alpha-Sulfonyl Anions. Fluoride-Promoted Intramolecular 1,2-Additions to Aldehydes as the Basis of a New Cyclopentenylation Strategy
M.B. Anderson; P.L. Fuchs
J. Org. Chem. 1990, 55, 337-342 [Syntheses Via Vinyl Sulfones 37, Cytochalasin Support Studies 13]
103. The Intramolecular Migration of a Trimethylsilyl Group Located alpha to a Sulfone in Substituted Cyclohexyl Systems
K.V. Wood, A.P. Rothwell, M.B. Anderson, P.L. Fuchs
Rapid Commun. Mass. Spectrom. 1990, 4, 1-4
104. Annulation Reactions of Ortho-Chloromethyl Aryl Cuprates
C.R. Nevill, Jr., P.L. Fuchs
Syn. Comm. 1990, 20, 761-772 [Syntheses Via Vinyl Sulfones 39]
105. Mass Spectra of Substituted o-Trimethylsilylphenyl Sulfones
K.V. Wood, A.P. Rothwell, M.B. Anderson, M. Lamothe, P.L. Fuchs
Organic Mass Spectrometry 1990, 25, 423-425
106. Fluoride Ion Mediated Intramolecular Sulfenylation of alpha-Silyl Sulfones: Ramberg-Bäcklund Annulation to Exocyclic Fused Olefins
D. Scarpetti, P.L. Fuchs
J. Amer. Chem. Soc. 1990, 112, 8084-8090 [Syntheses Via Vinyl Sulfones 38, Cytochalasin Support Studies 14]
107. Understanding Organic Chemistry at the Molecular Level, 2nd Ed.
P. L. Fuchs
1990, Stipes Publishing Co., 10-12 Chester Street, Champaign, IL 61820
108. Total Synthesis of the Cephalotaxus Alkaloids dl-Cephalotaxine, dl-11-Hydroxycephalotaxine, and dl-Drupacine
T.P. Burkholder, P.L. Fuchs
J. Am. Chem. Soc. 1990, 112, 9601-9613 [Syntheses Via Vinyl Sulfones 40]
109. Accessing the Information in the Zymate Dictionary with a Personal Computer
D.A. Lantrip, P.L. Fuchs, G.W. Kramer
Laboratory Robotics and Automation 1990, 2, 19-22 [PASS 19]
110. Mass Spectra of omega-Substituted alpha-Trimethylsilyl Phenylsulfones
K.V. Wood, A.P. Rothwell, D. Scarpetti, P.L. Fuchs
Organic Mass Spectrometry 1991, 26, 47-49
111. Triply-Convergent Total Synthesis of a Homochiral Benzoindane-fused Prostacyclin Analog
S.A. Hardinger, J.A. Jakubowski, P.L. Fuchs
Biomed. Chem. Lett. 1991, 1, 73-76 [Syntheses Via Vinyl Sulfones 30]
112. Total Synthesis of a Homochiral Arene-fused Prostacyclin Analog
C.R. Nevill, Jr., T.F. Braish, J.A. Jakubowski, P.L. Fuchs
Biomed. Chem. Lett. 1991, 1, 77-78 [Syntheses Via Vinyl Sulfones 31]
113. Triply-Convergent Syntheses of Two Homochiral Arene-fused Prostacyclin Analogs Related to U68,215
S. A. Hardinger, J.A. Jakubowski, P.L. Fuchs
Biomed. Chem. Lett. 1991, 1, 79-82 [Syntheses Via Vinyl Sulfones 32]
114. Triply-Convergent Synthesis of Two Sets of Homochiral Cyclopent[a]indene Carbacyclin Analogs
C.R. Nevill, Jr., J.A. Jakubowski, P.L. Fuchs
Biomed. Chem. Lett. 1991, 1, 83-86 [Syntheses Via Vinyl Sulfones 33]
115. Controlled Endocyclic and Exocyclic gamma-Metalations of beta-substituted Cyclohexenyl Sulfones. Regiospecific Syntheses of gamma-oxygenated Cyclohexenyl Sulfones
S.W. Lee, P.L. Fuchs
Tetrahedron Lett. 1991, 32, 2861-2864. [Syntheses Via Vinyl Sulfones 43]
116. Scope and Limitations in the Use of alpha-Silyl and alpha-Stannyl Sulfones as Latent alpha-Sulfonyl Anions
M. Lamothe, M.B. Anderson, P.L. Fuchs
Syn. Comm. 1991, 21, 1675-1693. [Syntheses Via Vinyl Sulfones 41, Cytochalasin Support 15]
117. Intramolecular Acylation of an alpha-Sulfonyl Anion Generated via Halogen-metal Exchange of an alpha-Halosulfone Bearing an Unsymmetrical Anhydride
M.B. Anderson, M. Lamothe, P.L. Fuchs
Tetrahedron Lett. 1991, 32, 4457-4460 [Syntheses Via Vinyl Sulfones 42, Cytochalasin Support 16]
118. Understanding Organic Chemistry at the Molecular Level, 3rd Ed.
P. L. Fuchs
1991 Stipes Publishing Co., 10-12 Chester Street, Champaign, IL 61820
119. Triply-Convergent Synthesis of a Homochiral 3,3-Dimethyl, 15-Cyclohexyl Prostacyclin Analog
R.A. Berglund, T.F. Braish, J.A. Jakubowski, P.L. Fuchs
Biomed. Chem. Lett. 1991, 1, 649-652 [Syntheses Via Vinyl Sulfones 43]
120. Synthesis of Tertiary Alcohols via the Use of the Allyldimethylsilyl Moiety as a Latent Hydroxyl Group in the Kumada-Fleming-Tamao Reaction
S.S. Magar, P.L. Fuchs
Tetrahedron Lett. 1991, 32, 7513-7516
121. Intramolecular 1,4-addition of a-Heteroatom Radicals to beta,beta-disubstituted enones. Application to a Tandem Cyclization
S. Kim, P.L. Fuchs
J. Am. Chem. Soc. 1991, 113, 9864-9865
122. Bis-Alkylation of Dimetallated Phenylsufonylmethyl Triflone. A n+1 Annulation Strategy for Synthesis of Cyclic Vinyl Sulfones
S.S. Magar, P.L. Fuchs
Tetrahedron Lett. 1992, 33, 745-748 [Triflones 1, Syntheses Via Vinyl Sulfones 44]
123. Evidence for a Double Intramolecular Trimethylsilyl Rearrangement
K.V. Wood, A.P. Rothwell, D. Scarpetti, P.L. Fuchs
Organic Mass Spectrometry 1992, 27, 97-98
124. Synthesis and Pharmacological Evaluation of Nonacyclic and Trisdecacyclic Pyrazines Related to Cephalostatin
Y. Pan, R. L. Merriman, L. R. Tanzer, P. L. Fuchs
Bioorg. & Med. Chem. Lett. 1992, 967-972 [CSTAT 1]
125. Synthesis of Phorbol C-Ring Analogs: A Biomimetic Model Study on the Phorbol to 12-Hydroxydaphnetoxin Conversion
Sharad S. Magar, R.C. Desai, P.L. Fuchs
J. Org. Chem. 1992, 57, 5360-5369
126. Use of beta-silylethyl Vinyl Ketone as a beta-Hydroxyethyl Vinyl Ketone Synthon in the Robinson Annulation Reaction
S. Kim, G. Emeric, P. L. Fuchs
J. Org. Chem. 1992, 57, 7362-7364
127. Intramolecular Photocyclization of Aryl Vinyl Sulfones
C. Li, P. L. Fuchs
Tetrahedron Lett. 1993, 34, 1855-1858 [Syntheses Via Vinyl Sulfones 46]
128. Tetramethylguanidinium Azide as A New Reagent for the Stereoselective Synthesis of Glycosyl Azides
C. Li, A. Arasappan, P. L. Fuchs
Tetrahedron Lett. 1993, 34, 3535-3538
129. Intramolecular Oxygen Versus Carbon Alkylation of Naphthoate Esters. A Caveat on the Mechanistic Aspects of Neocarzinostatin Chemistry
M. Lamothe, P. L. Fuchs
J. Am. Chem. Soc. 1993, 115, 4483-4496 [Syntheses Via Vinyl Sulfones 45]
130. Oxidation and Reduction Reactions of Highly Functionalized Allyl Stannanes. Bicyclic and Tricyclic alpha-Stannylmethyl Enones Prepared Via the Robinson Annulation Reaction of beta'-Stannylethyl Vinyl Ketone
S. Kim, P. L. Fuchs
J. Am. Chem. Soc. 1993, 115, 5934-5940
131. Regiospecific Silver[I] Promoted, Palladium[0]-Catalyzed Intramolecular Addition of Aryl Iodides to Vinyl Sulfones
Z. Jin, P. L. Fuchs
Tetrahedron Lett. 1993, 34, 5205-5208 [Syntheses Via Vinyl Sulfones 47]
132. Comparison of Vinyl Organolithium and Organopalladium Reagents for Intramolecular Conjugate Addition to Vinyl Sulfones
S. W. Lee, P. L. Fuchs
Tetrahedron Lett. 1993, 34, 5209-5212 [Syntheses Via Vinyl Sulfones 48]
133. Synthesis of a 17-Deoxy, C-14,15-Dihydro Derivative of the North Spiroketal Moiety of the Cephalostatins. Conversion to a (+)-Trisdecacyclic C2 Symmetrical Pyrazine
J. U. Jeong, P. L. Fuchs
J. Am. Chem. Soc. 1994, 116, 773-774 [CSTAT 2]
134. Synthesis of 15-Deoxy-16beta-Ethoxybruceantin and Synthetic Efforts toward Bruceantin
C. K.-F. Chiu, S. V. Govindan, P. L. Fuchs
J. Org. Chem. 1994, 59, 311-323
135. Conversion of Amides and Lactams to Thioamides and Thiolactams Using Hexamethyldisilathiane
D. C. Smith, S. W. Lee, P. L. Fuchs
J. Org. Chem. 1994, 59, 348-354
136. The Use of Tetramethylguanidinium Azide in Non-halogenated Solvents Avoids Potential Explosion Hazards
C. Li, T.-L. Shih, J. U. Jeong, A. Arasappan, P. L. Fuchs
Tetrahedron Lett. 1994, 35, 2645-2646
137. Understanding Organic Chemistry at the Molecular Level, 4th Ed.
P. L. Fuchs
1994 Stipes Publishing Co., 10-12 Chester Street, Champaign, IL 61820
138. Biochemical and Pharmacological Activity of Arene-Fused Prostacyclin Analogues on Human Platelets
J. A. Jakubowski, B. G. Utterback, D. E. Mais, S. A. Hardinger, T. F. Braish, C. R. Nevill, P. L. Fuchs
Prostaglandins 1994, 47, 189-200 [Syntheses Via Vinyl Sulfones 49]
139. Synthesis and Pharmacological Evaluation of Vinyl Sulfone Based Anticancer Agents
C. Li, A. Mahadevan, A. Arasappan, J. R. Phillips, R. L. Merriman, L. R. Tanzer, P. L. Fuchs
Bioorg. Med. Chem. Lett. 1994, 4, 1585-1590 [Syntheses Via Vinyl Sulfones 50]
140. Amelioration of the Leaving Group Ability of the Aryl Sulfone Moiety via Intramolecular Oxygen Silylation
P. C. Van Dort, P. L. Fuchs
J. Am. Chem. Soc. 1994, 116, 5657-5661 [Syntheses Via Vinyl Sulfones 51]
141. A Highly Efficient Synthesis of beta-Substituted Six- and Seven-Membered-Ring Enones via Carbon Alkylation of gamma-Methoxy Allylsulfonyl Anions.
Z. Jin, P. L. Fuchs
J. Am. Chem. Soc. 1994, 116, 5995-5996 [Syntheses Via Vinyl Sulfones 52]
142. Methanesulfenyl Triflate Promoted Iminosulfenylation of an Allylic Trichloroacetimidate. An Efficient and Stereospecific Total Synthesis of (+) Mannostatin A
C. Li, P. L. Fuchs
Tetrahedron Lett. 1994, 35, 5121-5124
143. Spiroketal Equilibration: Interconversion of 1,6-Dioxaspiro[4.4]nonanes and 1,6-Dioxaspiro[4.5]decanes. Implications for the Synthesis of Cephalostatin 7
J. U. Jeong, P. L. Fuchs
Tetrahedron Lett. 1994, 35, 5385-5388 [CSTAT 3]
144. A Mild and Convenient Synthesis of Functionalized Methyl Triflones and Vinyl Triflones
A. Mahadevan, P. L. Fuchs
Tetrahedron Lett. 1994, 35, 6025-6028 [Triflones 2, Syntheses Via Vinyl Sulfones 53]

145.

Intramolecular Conjugate Addition of Allylic Trichloroacetimidates to Cycloalkenyl Sulfones. A Regiospecific and Stereoselective Synthesis of Amino Alcohol Derivatives
C. Li, P. L. Fuchs
Syn. Lett. 1994, 629-630 [Syntheses Via Vinyl Sulfones 54]

146. Application of the Reich Iodoso syn-Elimination for the Preparation of an Intermediate Appropriate for the Synthesis of both Hexacyclic Steroidal Units of Cephalostatin 7
S. Kim, P. L. Fuchs
Tetrahedron Lett. 1994, 35, 7163-7166 [CSTAT 4]
147. Silver Fluoroborate Promoted Sulfur Alkylation of beta-Silyl Ethyl Sulfides. Selective Synthesis of beta-Thioglycosides
A. Mahadevan, C. Li, P. L. Fuchs
Syn. Comm. 1994, 24, 3099-3107
148. Regiospecific 4,6-Functionalization of Pyranosides via Dimethylboron Bromide-Mediated Cleavage of Phthalide Orthoesters
A. Arasappan, P. L. Fuchs
J. Am. Chem. Soc. 1995, 117, 177-183
149. New Synthetic Methods Exploiting Vinyl Sulfones Discovered During the Synthesis of a Natural Product
Z. Jin, P. C. Van Dort, P. L. Fuchs
Phosphorus, Sulfur and Silicon 1994, 95, 1-19 [Syntheses Via Vinyl Sulfones 55]
150. Addition of gamma-Methoxy Allylsulfonyl Anions to Cyclopentenyl Phenyl Sulfones. A Facile Synthesis of beta-Cyclopentenyl-Substituted Dienones and Trienones
Z. Jin, P. L. Fuchs
J. Am. Chem. Soc. 1995, 117, 3022-3028 [Syntheses Via Vinyl Sulfones 56]
151. A Facile Synthesis of Allyl, gamma-Iodoallyl, and Cyclopropyl Triflones via Radical-Mediated Atom-Transfer Addition of Iodomethyl Triflone to Olefins and Acetylenes
A. Mahadevan, P. L. Fuchs
J. Am. Chem. Soc. 1995, 117, 3272-3273 [Triflones 3, Syntheses Via Vinyl Sulfones 5]
152. Chromium [II]-Mediated Reductive Cleavage of a Tertiary Halide Bearing Three beta-alkoxy Groups. Synthesis of the North Hexacyclic Steroid Unit of the Cephalostatin Family
S. Kim, S. C. Sutton, P. L. Fuchs
Tetrahedron Lett. 1995, 36, 2427-2430 [CSTAT 5]
153. Synthesis of the South Hexacyclic Steroid Unit of Cephalostatin 7
J. U. Jeong, P. L. Fuchs
Tetrahedron Lett. 1995, 36, 2431-2434 [CSTAT 6]
154. A Triply Convergent Total Synthesis of a Symchiral Pyrrolidine-Fused Prostacyclin Analog
D. C. Smith, P. L. Fuchs
J. Org. Chem. 1995, 40, 2692-2703 [Syntheses Via Vinyl Sulfones 58]
155. Conversion of Vinyl Sulfones to Regiospecifically Functionalized Trisubstituted Olefins
S. H. Kim, Z. Jin, S. Ma, P. L. Fuchs
Tetrahedron Lett. 1995, 36, 4013-4014 [Syntheses Via Vinyl Sulfones 60]
156. Synthesis of Beta-Substituted Cyclopentenones via Carbon Alkylation of Metalated Gamma-Methoxycyclopentenyl Phenylsulfonyl Anion
S. H. Kim; Z. Jin; P. L. Fuchs
Tetrahedron Lett. 1995, 36, 4537-4538 [Syntheses Via Vinyl Sulfones 59]
157. Biomimetic Total Syntheses of (+)-Cephalostatin 7, (+)-Cephalostatin 12, and (+)-Ritterazine K
Jeong, J. U.; Sutton, S. C.; Kim, S.; Fuchs, P. L.
J. Am. Chem. Soc. 1995, 117, 10157-10158 [CSTAT 9]
158. Synthesis of a C14',15' Dihydro Derivative of the South Hexacyclic Steroid Unit of Cephalostatin 1. Part I: Regiospecific Rh[II]-Mediated Intermolecular Oxygen Alkylation of a Primary Neopentyl Alcohol
Bhandaru, S.; Fuchs, P. L.
Tetrahedron Lett. 1995, 36, 8347-8350 [CSTAT 7]
159. Synthesis of a C14',15' Dihydro Derivative of the South Hexacyclic Steroid Unit of Cephalostatin 1. Part II: Spiroketal Synthesis and Stereochemical Assignment by NMR Spectroscopy
Bhandaru, S.; Fuchs, P. L.
Tetrahedron Lett. 1995, 36, 8351-8354 [CSTAT 8]
160. Conversion of d-(sulfonyl)amino-alpha-epoxy Ketones to Bicyclic Ketopyrroles via Intramolecular Conjugate-addition to Azoene Intermediates. Synthesis of the Bicyclic Ketopyrrole Core of the 1-Azafulvene Roseophilin
Kim, S. H.; Fuchs, P. L.
Tetrahedron Lett. 1996, 37, 2545-2548 [Syntheses Via Vinyl Sulfones 63]
161. Stereo- and Regiospecific Syntheses of alpha- and beta-Substituted Vinyl and Dienyl Triflones via the Stille Reaction
Xiang, J. S.; Mahadevan, A.; Fuchs, P. L.
J. Am. Chem. Soc. 1996, 118, 4284-4290 [Triflones 4, Syntheses Via Vinyl Sulfones 62]
162. Alkynylation of C-H Bonds via Reaction with Acetylenic Triflones
Gong, J.; Fuchs, P. L.
J. Am. Chem. Soc. 1996, 118, 4486-4487 [Triflones 5, Syntheses Via Vinyl Sulfones 61]
163. Phosphazene Base P2-Et Mediated Isomerization of Vinyl Sulfones to Allyl Sulfones
Jin, Z.; Kim, S. H.; Fuchs, P. L.
Tetrahedron Lett. 1996, 37, 5247-5248 [Syntheses Via Vinyl Sulfones 64]
164. Use of Phosphazene Base and Phase-Transfer Conditions for Regiospecific Alkylative Isomerization of Vinyl Sulfones Capable of Undergoing beta-Elimination Reactions
Jin, Z.; Fuchs,P. L.
Tetrahedron Lett. 1996, 37, 5249-5252 [Syntheses Via Vinyl Sulfones 65]
165. Palladium[0]-Mediated Aminospirocyclization of Tertiary Allylic Sulfones. Stereospecific Construction of the Azabicyclic Ring System of Cephalotaxine
Jin, Z.; Fuchs, P. L.
Tetrahedron Lett. 1996, 37, 5253-5256 [Syntheses Via Vinyl Sulfones 66]
166. Mechanistic Aspects of the C-H Alkynylation Reaction of Acetylenic Triflones. Determination of Phenyl Versus Cyclohexyl Migratory Aptitude for a Vinylidine Carbene
Xiang, J. S.; Fuchs, P. L.
Tetrahedron Lett. 1996, 37, 5269-5272 [Triflones 6, Syntheses Via Vinyl Sulfones 67]
167. Understanding Organic Chemistry at the Molecular Level, 5th Ed.
P. L. Fuchs
1996, Stipes Publishing Co., 10-12 Chester Street, Champaign, IL 61820
168. An Efficient Protocol for the Synthesis of Unsymmetrical Pyrazines. Total Synthesis of Dihydrocephalostatin 1
Guo, C.; Bhandaru, S.; Fuchs, P. L. ; Boyd, M. R.
J. Am. Chem. Soc. 1996, 118, 10672-10673 [CSTAT 10]
169. Alkenylation of C-H Bonds via Reaction with Vinyl and Dienyl Triflones. Stereospecific Synthesis of Trisubstituted Vinyl Triflones via Organocopper Addition to Acetylenic Triflones
Xiang, J.; Fuchs, P. L.
J. Am. Chem. Soc. 1996, 118, 11986-11987 [Syntheses Via Vinyl Sulfones 68, Triflone Chemistry 7]
170. Alkynylation of Aldehydic C-H Bonds via Reaction with Acetylenic Triflones
Gong, J.; Fuchs, P. L.
Tetrahedron Lett. 1997, 38, 787-790 [Syntheses Via Vinyl Sulfones 70, Triflone Chemistry 9]
171. Application of the Grubbs Ring-Closing Metathesis for the Construction of a Macrocyclic Ansa-Bridge. Synthesis of the Tricyclic Core of Roseophilin
Kim, S. H.; Figueroa, I.; Fuchs, P. L.
Tetrahedron Lett. 1997, 38, 2601-2604 [Syntheses Via Vinyl Sulfones 71]
172. Stereospecific Alkenylation of C-H Bonds via Reaction with b-Heteroatom-Functionalized Trisubstituted Vinyl Triflones
Xiang, J.; Jiang, W.; Gong, J.; Fuchs, P. L.
J. Am. Chem. Soc. 1997, 119, 4123-4129 [Syntheses Via Vinyl Sulfones 69, Triflone Chemistry 8]
173. Scope and Limitations in the Jacobsen Epoxidation of Dienyl Sulfones
Hentemann, M. F.; Fuchs, P. L.
Tetrahedron Lett. 1997, 38, 5615-5618 [Synthesis Via Vinyl Sulfones 74]
174. Scope and Limitations of Functionalized Acetylenic Triflones in the Direct Alkynylation of C-H Bonds
Xiang, J.; Jiang, W.; Fuchs, P. L.
Tetrahedron Lett. 1997, 38, 6635-6638 [Synthesis Via Vinyl Sulfones 75, Triflone Chemistry 10]
175. Design and Synthesis of [IIIIIn]DTPA-Folate for Use as a Tumor-Targeted Radiopharmaceutical
Wang, S.; Luo, J.; Lantrip, D. A.; Waters, D. J.; Mathias, C. J.; Green, M. A.; Fuchs, P. L.; Low, P. S.
Bioconjugate Chem. 1997, 8, 673-679 [FMDD 1]
176. Efficient Syntheses of Pyrofolic Acid and Pteroyl Azide, Reagents for the Production of Carboxyl-Differentiated Derivatives of Folic Acid
Luo, J.; Smith, M. D.; Lantrip, D. A.; Wang, S.; Fuchs, P. L.
J. Am. Chem. Soc. 1997, 119, 10004-10013 [FMDD 2]
177. Sulfones as Radical Progenitors: An Unprecedented Example of Homolytic Sulfone Cleavage Facilitated by o-Stannyl Substitution of Aryl Sulfones
P. C. Van Dort; P. L. Fuchs
J. Org. Chem. 1997, 62, 7137-7141 [Synthesis Via Vinyl Sulfones 72]
178. Free Radical Self-Immolative 1,2-Elimination and Reductive Desulfonylation of Aryl Sulfones Promoted by Intramolecular Reactions with Ortho-Attached Carbon-Centered Radicals
P. C. Van Dort; P. L. Fuchs
J. Org. Chem. 1997, 62, 7142-7147 [Synthesis Via Vinyl Sulfones 73]
179. The First Synthesis of the Aglycone of the Potent Anti-Tumor Steroidal Saponin OSW-1
Guo, C; Fuchs, P.L.
Tetrahedron Lett. 1998, 39, 1099-1102 [CSTAT 12]
180. Interphylal Product Splicing: The First Total Synthesis of Cephalostatin 1, the North Hemisphere of Ritterazine G, and the Highly Active Hybrid Analogue, Ritterostatin GN1N  
LaCour, T.G.; Guo, C.; Bhandaru, S.; Boyd, M.R.; Fuchs, P.L.
J.Am.Chem.Soc. 1998, 120, 692-707 [CSTAT 11]
181. Use of Allylic Triflones for Allylation of C-H Bonds
Xiang, J.; Evarts, J.; Rivkin, A.; Curran, D.P.; Fuchs, P.L.
Tetrahedron Lett. 1998, 39, 4163-4166 [Synthesis Via Vinyl Sulfones 76, Triflone Chemistry 11]
182. Chemospecific Alkynylation of Organic Iodides
Xiang, J.; Fuchs, P.L.
Tetrahedron Lett. 1998, 39, 8597-8600 [Synthesis Via Vinyl Sulfones 77, Triflone Chemistry 12]
183. On the Relationship of OSW-1 to the Cephalostatins
Guo, C; LaCour, T.G.; Fuchs, P.L.
Bioorg. Med. Chem. Lett. 1999, 9, 419-424 [CSTAT 15]
184. Synthesis of the North 1 Unit of the Cephalostatin Family from Hecogenin Acetate
Kim, S.; Sutton, S.C.; Guo, C.; LaCour, T.G.; Fuchs, P.L.
J.Am.Chem.Soc. 1999, 121, 2056-2070 [CSTAT 13]
185. Synthesis of the South Unit of the Cephalostatin 7.  Total Synthesis of (+)-Cephalostatin 7, (+)-Cephalostatin 12, and (+)-Ritterazine K
Jeong, J.U.; Guo, C.; Fuchs, P.L.
J.Am.Chem.Soc. 1999, 121, 2071-2084 [CSTAT 14]
186. Synthesis of 6-Carbon Termini-Differentiated Stereotriads via Symchiral 2-Trifoxy-1,3-cyclohexadiene monoepoxide
Hentemann,M.; Fuchs, P.L.
Tetrahedron Lett. 1999, 40, 2699-2702 [Synthesis Via Vinyl Sulfones 78]
187. Synthesis of a Family of Epoxyvinyltriflate Stereotetrads from 4-Hydroxycyclohex-2-ene-1-one
Evarts, J.B., Jr.; Fuchs, P.L. 
Tetrahedron Lett. 1999, 40, 2703-2706 [Synthesis Via Vinyl Sulfones 79]
188. Concurrent Ring Opening and Halogenation of Spiroketals
LaCour, T.G; Fuchs, P.L. 
Tetrahedron Lett. 1999, 40, 4655-4658 [CSTAT 17]
189. Reduction of Azides to Primary Amines in Substrates Bearing Labile Ester Functionality. Synthesis of a PEG-Solubilized, "Y"-Shaped Iminodiacetic Acid Reagent for Preparation of Folate-Tethered Drugs
Lee, J.W.; Fuchs, P.L.
Organic Lett. 1999, 1, 179-181 [FMMD 3]
190. Asymmetric Epoxy Cyclohexenyl Sulfones: Readily Accessible Progenitors of Stereodefined Six-Carbon Arrays
Hentemann, M.; Fuchs, P.L. 
Organic Lett. 1999, 1, 355-357 [Synthesis Via Vinyl Sulfones 81]
191. On Topography and Functionality in the B-D Rings of Cephalostatin Cytotoxins
LaCour, T.G; Guo, C.; Ma, S.; Jeong, J.U.; Boyd, M.R.; Matsunaga, S; Fusetani, N.; Fuchs, P.L. 
Bioorg. Med. Chem. Lett. 1999, 9, 2587-2592 [CSTAT 16]
192. Consequences of Acid Catalysis in Ring Opening and Halogenation of Spiroketals
LaCour, T.G.; Fuchs, P.L. 
Organic Lett. 1999, 1, 1815-1818 [CSTAT 18]
193. Outer-Ring Stereochemical Modulation of Cytotoxicity in Cephalostatins
LaCour, T.G.; Fuchs, P.L.
Organic Lett.2000, 1, 33-36 [CSTAT 19]
194. Synthesis of Enantiopure Termini-Differentiated Heptane Stereotriads
Jiang W.; Lantrip, D.A.; Fuchs, P.L.
Organic Lett.2000, 2, 2181-2184 [Synthesis via Vinyl Sulfones 82]
195. Synthesis and Oxidation Reactions of Cycloheptatrienyl Sulfones
Tong, Z.W.; Chen, Y.Z.; Hentemann, M.F.; Fuchs, P.L.
Tetrahedron Lett.2000, 41, 7795-7799 [Synthesis via Vinyl Sulfones 83]
196. An Efficient and Convenient Synthesis of Enantiopure 4-(t-butyldimethylsilyloxy)-cyclohex-2-en-1-one: a Formal Synthesis of (±)-Mesembranol
Evarts, J.B, Jr.; Fuchs, P.L.
Tetrahedron Lett.2001, 42, 3673-3675 [Synthesis via Vinyl Sulfones 84]
197. Increase in Intricacy - a Tool for Evaluating Organic Syntheses
Fuchs, P.L.
Tetrahedron 2001, 57, 6855-6875
198. Relative Reactivity of anti- and syn-Oximino Carbonates and Carbamates of 2-Pyridylacetic Acid Esters
Kim, H.Y.; Lantrip, D.A.; Fuchs, P.L.
Organic Lett.2001, 3, 2137-2140 [FMMD 4]
199. Economical and Environmentally Friendly Syntheses of 2-(Phenylsulfonyl)-1,3-cyclohexadiene and 2-(Phenylsulfonyl)-1,3-cycloheptadiene
Meyers, David J.; Fuchs, P.L.
J.Org.Chem.2002, 67, 200-204 [Synthesis via Vinyl Sulfones 85]
200. Redox Refunctionalization of Steroid Spiroketals.Structure Correction of Ritterazine M
Lee, Seongmin; LaCour, Thomas G.; Lantrip, D.A.; Fuchs, P.L.
Organic Lett.2002, 4, 313-316 [CSTAT 20]
201. The First Total Synthesis of (Corrected) Ritterazine M
Lee, Seongmin; Fuchs, P.L.
Organic Lett.2002, 4, 317-318 [CSTAT 21]
202. Dyotropic Rearrangement Facilitated Proximal Functionalization and Oxidative Removal of Angular Methyl Groups: Efficient Synthesis of 23'-Deoxy Cephalostatin 1 Analogues
Li, Wei; LaCour, Thomas G.; Fuchs, P.L.
J.Am.Chem .Soc.2002, 124(17), 4548-4549 [CSTAT 22]
203. Synthesis and Evaluation of Taxol-Folic Acid Conjugates as Targeted Antineoplastics
Lee, Jae Wook; Lu, June Y.; Low, P.S.; Fuchs, P.L.
Bioorganic & Medicinal Chemistry 2002, 10(7), 2397-2414 [FMMD 5]
204. Synthesis of Highly Substituted Enantiopure C6 and C7 Enones
Evarts, J.; Torres, E.; Fuchs, P.L.
J.Am.Chem.Soc.2002, 124, 11093-11101 [Synthesis via Vinyl Sulfones 86]
205. Chemospecific Chromium[VI] Catalyzed Oxidation of C-H Bonds at -40 C
Lee, S.; Fuchs, P.L.
J.Am.Chem .Soc. 2002, 124, 13978-13979 [CSTAT 23]
206. Functionality Propagation by Alkylation Oxidation of Cross-Conjugated Dienyl Sulfones. Application to the Synthesis of Polypropionate Stereopentads
Torres, E; Chen, Y.; Kim, I.C.; Fuchs, P.L.
Angew.Chem.Int.Ed.2003, 124, 3124-3131
207. New Oxidative Tools for the Functionalization of the Cephalostatin North 1 Hemisphere
Lee, J.S.; Fuchs, P.L.
Organic Lett. 2003, 5, 2247-2250 [CSTAT 24]
208. An Efficient Synthesis of the C-23 Deoxy, 17alpha-Hydroxy South 1 Hemisphere and its Cephalostatin 1 Analog
Li, W.; Fuchs, P.L.
Organic Lett.2003, 5, 2849-2852 [CSTAT 26]
209. A New Protocol of In-situ Dioxarane Reactions: Stiochiometric in Oxone and Catalytic in Fluoridated Acetophenones
Li, W.; Fuchs, P.L.
Organic Lett.2003, 5, 2853-2856 [CSTAT 27]
210. Synthesis of Termini-Differentiated 6-Carbon Stereotetrads: An Alkylative Oxidation Strategy for Preparation of the C21-C26 Segment of Apoptolidin
Chen, Y.; Evarts, J.B., Jr.; Torres, E.; Fuchs, P.L.
Organic Lett. 2002, 4, 3571-3574 [Synthesis via Vinyl Sulfones 88]
211. Synthesis of Allyl Phosphine Oxides/Boranes via Horner Reaction of Bis(diphenylphosphine)ethane Monoxide Reagent with an Aldehyde
Cacatian, S.; Fuchs, P.L.
Tetrahedron 2003, 59, 7177-7187
212. Polyphosphoric Acid Trimethylsilyl Ester Promoted Intramolecular Acylation of an Olefin by a Carboxylic Acid: Convenient Construction of C-18 Functionalized D14-Hecoginin Acetate
Li, W.; Fuchs, P.L.
Organic Lett.2003, 5, 4061-4064 [CSTAT 29]
213. Trifluoroacetyl Trifluoromethanesulfonate (TFAT): An Efficient Agent for Ring Opening of Spiroketals
Lee, J.S.; Fuchs, P.L.
Organic Lett.2003, 5, 3619-3622 [CSTAT 30]
214. gamma-Allyl Phosphinoyl Phenyl Sulfone (GAPPS): A Conjunctive Reagent for the Synthesis of EE, EZ, and ET 1,3 -Dienes
Li, X.; Lantrip, D.; Fuchs, P.L.
J.Am.Chem.Soc.2003, 125, 14262-14263 [Synthesis via Vinyl Sulfones 87]
215. Synthesis of Enantiopure Five-Carbon Stereodiads Applicable for the Preparation of the Mycolactones
Tong, Z.; Ma, S.; Fuchs, P.L.
J.Sulfur Chemistry 2004, 1, 1-7 [Synthesis via Vinyl Sulfones 84]
216. An Efficient C-H Oxidation Protocol for the alpha-Hydroxylation of Cyclic Steroidal Ethers
Lee, S.M.; Fuchs, P.L.
Organic Lett. 2004, 6, 1437-1440 [CSTAT 31]
217. Improved and Environmentally Friendly Large-Scale Preparation of Cyclohexadienyl-, Cycloheptadienyl Sulfone and Enantiopure Cycloheptyl Sulfones
Park, T.; Torres, E.; Fuchs, P.L.
Synthesis 2004, 1895-1900
218. 3,3,3-Trichloropropyl-1-triphenylphosphorane: A Reagent for the Synthesis of (Z)-1,3-Enynes, (Z,Z)-1-Chloro-1,3-dienes, and 1,3-Diynes
Karatholuvhu, M.S.; Fuchs, P.L.
J.Am.Chem.Soc. 2004, 126, 14314-14315
219. A biomimetically inspired, efficient synthesis of the south 7 hemisphere of cephalostatin 7
Lee, J. S.; Fuchs, P. L.
J.Am.Chem.Soc. 2005, 127, 13122-1312
220. Double Lawton S(N)2 ' addition to epoxyvinyl sulfones: Selective construction of the stereotetrads of aplyronine A
El-Awa, A.; Fuchs, P. L.
Organic Lett. 2006, 8, 2905-2908
221. A Concise Total Synthesis of DL-Histrionicotoxin
Karatholuvhu, M.; Sinclair, A.; Newton, A. F.; Alcaraz, M.-L.; Stockman, R. A.; Fuchs, P. L.
J. Am. Chem. Soc., 2006, 128, 12656 -12657
222. In situ nitrosonium ion generation - alpha-Oximinylation of enol ethers from steroidal spiroketals: Introduction of C23 (R)-OH in cephalostatin intermediates
Lee, S.; Fuchs, P. L.
Can. J. Chem. 2006, 84, 1442-1447
223. Handbook of Organic Reagents: Reagents for Direct Functionalization of C-H Bonds
Fuchs, Philip (ed.)
Book, 2006 John Wiley, New York, Great Britain
224. Lactol-directed osmylation. Stereodivergent synthesis of four C-19,20 apoptolidin diols from a single allylic hemiacetal
Kim, Y.; Fuchs, P. L.
Organic Lett. 2007, 9, 2445-2448
225. Ruthenium-catalyzed mild C-H oxyfunctionalization of cyclic steroidal ethers
Lee, J. S.; Cao, H.; Fuchs, P. L.
J. Org. Chem. 2007, 72, 5820-5823 [CSTAT 34]
226. Conversion of cyclic vinyl sulfones to transposed vinyl phosphonates
Noshi, M. N.; El-Awa, A.; Torres, E.; Fuchs, P. L.
J. Am. Chem. Soc. 2007, 129, 11242-11247 [Synthesis via Vinyl Sulfones 93]
227. Asymmetric synthesis of all eight seven-carbon dipropionate stereotetrads
El-Awa, A.; du Jourdin, X. M.; Fuchs, P. L.
J. Am. Chem. Soc. 2007, 129, 9086-9093
228. Second-generation synthesis of syn- and anti-cycloheptadienylsulfone polyketide stereodiads
Noshi, M. N.; El-Awa, A.; Fuchs, P. L.
J. Org. Chem.  2008, 73, 3274-3277
229. Synthesis of C14,15-Dihydro-C22,25-epi North Unit of Cephalostatin 1 via "Red-Ox" Modifications of Hecogenin Acetate
Lee, S. M.; Jamieson, D.; Fuchs, P. L.
Organic Lett. 2009, 11, 5-8
230. Designer Discodermolide Segments via Ozonolysis of Vinyl Phosphonates
du Jourdin, X. M.; Noshi, M.; Fuchs, P. L.
Organic Lett. 2009, 11, 543-546
231. Encyclopedia of Reagents for Organic Synthesis (EROS), 2nd Ed.,
Wiley Interscience, L. A. Paquette; D. Cruch; P. L. Fuchs; G. Molander, Eds. 2009
232. Chemistry of Trisdecacyclic Pyrazine Antineoplastics: The Cephalostatins and Ritterazines
Lee, S.; LaCour, T. G.; Fuchs, P. L.
Chem. Rev. 2009, 109, 2275-2314
233. Evolving Organic Synthesis Fostered by the Pluripotent Phenylsulfone Moiety
El-Awa, A.; Noshi, M. N.; du Jourdin, X. M.; Fuchs, P. L.
Chem. Rev. 2009, 109, 2315-2349
234. Reagent-Directed Allylic Quadraselection. Chemoselective Anti- and Syn-Lawton SN2´ Methylation of Sevel-Membered Epoxyvinylsulfones
W. P. Hong; A. El-Awa; P. L. Fuchs
J. Am. Chem. Soc. 2009, 131, 9150-9151