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Molecules & Ions

We can predict the structure around atoms in molecules such as H2O or in covalent polyatomic ions such as SO42- using Lewis formulas. However, we CANNOT use Lewis formulas to predict the structure of ionic compounds because these compounds do not contain molecules. Compare solid HCl with solid NaCl and solid CO2 (dry ice) with solid CaF2, for example.

A Very Small Chunk of Solid HCl

HCl is a molecular compound. Solid HCl consists of a repeating array of HCl molecules.

A Very Small Chunk of Solid NaCl

NaCl is an ionic compound. Solid NaCl consists of a stack of Na+ ions and Cl- ions. There are no molecules or covalent bonds in NaCl.

A Very Small Chunk of Solid CO2

CO2 is a molecular compound. Solid CO2 consists of a repeating array of CO2 molecules.

A Very Small Chunk of Solid CaF2

CaF2 is an ionic compound. There are no CaF2 molecules or covalent bonds in solid CaF2.

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